固载型离子液体催化合成碳酸酯的研究-化学工艺专业论文.docxVIP

ABSTRACT Ionic liquids are liquid salts at room temperature which are composed by anions and cations，and they have important meaning and application for the green chemical engineering. 丁he ionic liquids have excellent catalytic activity to the cycloaddition of carbon dioxide and epoxides，and the C02 are founded that which can dissolved in ionic Iiquids largely by the decades of research. So，the ionic liquids have been the aroused general interest by the scientists. But there are also many deficiencies on the 、 ionic liquids. For example，the high price，the high usage，uneasily separated and ‘purified and so on. So it is a great interest by the scientists on that the ionic liquids are immobilized to the inorganic porous materials or polymer materials to been the ‘ 4 heterogeneous catalyst by the adsorption method or bonding method. In this paper，three types of ionic Iiquids with imidazole cation immobilized to the Inorganic silica were synthesized by the author ([mim ]Cl，[mim]B日，[mim]PF6)，and the molecular structures were confirmed by FT-IR， EA and CNMR， etc. For optimizing the reaction condition，the influence of several 臼ctors on reaction was studied，and we concluded that when the Immobilized ionic liquids were used as catalyst only，the conversion ofthe Propylene oxide(PO) is only 67.74%.But when the promoter AICh were added to the action，the conversion is greatly improved. So the final satisfied reaction condition was obtained in 4 hours at 120.C，3MPa of carbon dioxide with 2.0g propylene oxide，0.03g AICh and O.3g catalyst [mim]CI. In this condition，the conversion and selection of propylene oxide and propylene carbonate were 99.74% and over 99.3%.What is more，this ca阳lytic system can be recycled and reused for four runs without any significant loss of catalytic activity. In this paper，the author also makes the traditional cyc1oaddition reaction and transesterification into one-pot synthesis of dimethyl carbonate. For