分光光度法测定高纯度膨润土吸蓝量-Core.PDF

23 2 Vol. 23No.2 17 2014 3 CHEMICAL ANALYSIS AND METERAGE Mar. 2014 doi 10.3969j.issn2014.02.005 * 12 3 2 2 3 1. 361005 2. 361005 3. 361101 5 min4% 20 mL0.01 molL 30 mL 15 min4% 1.04% O652.1 A 1008 6145(2014)02 0017 03 Determination of the Methylene Blue Value of High Levels of Bentonite by Spectrophotometry 12 3 2 2 3 Huang Li , Gao Qianqian , Cai Yanping , Dong Qingmu , Liu Haibo 1. College of Chemistry and Chemical Engineering, Xiamen University, Xiamen361005, China;2. Xiamen Entry Exit Inspection and Quarantine Bureau, Xiamen361005, China;3. Xiamen Zijin Mining and Metallurgy Technology Co. Ltd., Xiamen361101, China AbstractSpectrophotometry was used to measure the methylene blue value of high purity bentonite, and the orthogonal tests were used to optimize and determine the optimal experimental conditions: the boiling time was 5 min, 4% sodium pyrophosphate solution was added to a volume of 20 mL, 0.01 molL methylene blue solution was added to the volume of 30 mL, shaking time was 15 min. Compared the spectrophotometry to traditional titration analysis, the relative error of the experimental results was less than 4% and the relative standard deviation was 1.04%, which was proved to be accurate and reliable to meet the analytical requirements. Keywordshigh purity bentonite; methylene blue value; orthogonal tests; spectrophotometry 1 100 g 1.1