流动注射偶合化学发光法快速测定食品塑料袋中可浸出有机-食品科学.PDF

※分析检测 食品科学 2010, Vol. 31, No. 20 367 王长青，高向阳 * ，石含玉 (河南农业大学食品科学技术学院，河南 郑州 450002) 建立一种食品包装袋中可浸出有机物质总量的新型分析方法。以食品塑料袋为样品，经超声波浸提后， 用微波压力密闭快速消解浸提液，利用鲁米诺 - 过氧化氢 - 铬偶合流动注射化学发光体系进行测定。结果表明：有 -10 -5 3+ -11 3+ 机物相当于铬(Ⅲ) 的线性范围为1.154 ×10 ～1.154 ×10 mol/L(1/3Cr ) ，铬(Ⅲ)检出限为4.476 ×10 mol/L(1/3Cr ) ， RSD 为 3.1%( n =3) 。该法灵敏度高，操作简便、测定快速、成本低廉，利于普及推广。 流动注射分析(FLA) ；偶合化学发光；鲁米诺体系；食品塑料袋；有机化合物总量 Rapid Determination of Total Organic Matter in Food Plastic Bag by Flow Injection Coupled with Chemiluminescence WANG Chang-qing ，GAO Xiang-yang* ，SHI Han-yu (College of Food Science and Technology, Henan Agricultural University, Zhengzhou 450002, China) Abstract ：The aim of the present study was to develop a novel analytical method for rapidly determining total organic matter in food plastic bag using flow injection coupled with chemiluminescence. Samples received ultrasonic-assisted extraction and subsequent microwave pressure digestion prior to the analysis with luminol-H2O2-Cr3+ flow injection chemiluminescence system. -10 -5 Chromium (Ⅲ) (considered equivalent to total organic matter) displayed a linear range of 1.154 ×10 to 1.154 ×10 mol/L 3+ -11 3+ (1/3Cr ) and a detection limit of 4.476 ×10 mol/L (1/3Cr ), with a relative standard deviation (RSD) of 3.1% (n = 3). The proposed method is characterized by high sensitivity, ease of operation, rapid determination and low cost. All these figures of merits benefit its promotion