角质酶表面活性剂体系对混合办公废纸的协同脱墨作用.docx

角质酶/表面活性剂体系对混合办公废 纸的协同脱墨作用 王凤 龙柱 吴美燕 陈杰 张辉 江南大学纺织服装学院造纸研究室江南大学生态纺 织教育部重点实验室南京林业大学江苏省制浆造纸 科学与技术重点实验室 摘要： 角质酶能够水解可溶性酯、不溶性甘油三酯和各种聚酯，因此可以水解油墨中的 连接料，有代替脂肪酶应用于废纸脱墨领域的潜能。利用角质酶和实验室复配得 到的表而活性剂协同应用于混合办公废纸脱墨领域，探讨其脱墨效果和最优工 艺，并与常用商业脂肪酶进行脱墨效果比较。结果表明，角质酶在酶用量10 U - g-1,酶处理时间30 min,酶处理温度50°C,表面活性剂用量0. 2%的条件下 可以达到最优效果。与脂肪酶/表面活性剂以及单独用表面活性剂脱墨相比，角 质酶脱墨后纸页的白度与油墨去除率更高，纸页的机械强度也较好。通过纸页性 能的对比和扫描电镜(SEM)观察，角质酶的脱墨效果较脂肪酶更佳，角质酶/ 表面活性剂体系对混合办公废纸脱墨效果较好。 关键词： 角质酶;表面活性剂;混合办公废纸;浮选脱墨; 作者简介：王凤(1991—),女，硕士研究生。 收稿日期：2017-06-15 基金：国家自然科学基金项目 Deinking of mixed office waste paper by cutinase/surfactant system WANG Feng LONG Zhu WU Meiyan CHEN Jie ZHANG Hui Labora toxy ofPapermak i ng, School of Textiles Clothing, Jiangnan University; Jiangsu Provincial Key Laboratory of Pulp and Paper Science and Technology, Nanjing Forestry University; Abstract： Cutinase is capable of hydrolyzing soluble esters, insoluble triglycerides and various polyesters, and thus it can hydrolyze the binder in the ink and have the potential to replace 1 ipase in the field of waste paper dcinking. Cutinasc and self-made surfactant was syncrgically used in deinking of office waste paper. The deinking effect and optimum process were discussed and compared with the conventional commercial lipase. The resuIts showed that the optimal effect of cutinase could be achieved under the conditions of enzyme dosage of 10 U ? g~l, enzyme treatment time of 30 min, enzyme trcatmcnt temperature of 50°C and surfactant dosage of 0. 2%. Compared with lipase/surfactant and surfactant deinking, the brightness and ink removal rate of paper after cutinase deinking were higher and the mechanical strength of paper was also greatly improved. By comparison of the paper performance and scanning electron microscopy (SEN) analysis, the dcinking effect of cutinase was better than that of lipase. Keyword： cutinase; surfdctnnt; mixed office waste paper; flotation deinking; Received： 2017-06-15 引言 废纸回收是造纸行业而临资源和能源短缺问题的一种有效解决方案。脱墨是废纸 回收过程的第一步也是极为重要的一步。目前用于混合办公废