煤沥青型焦制备与固结机理-中南大学学报.PDF

第 47 卷第 7 期 中南大学学报( 自然科学版) Vol.47 No.7 2016 年 7 月 Journal of Central South University (Science and Technology) July 2016 DOI: 10.11817/j.issn.1672-7207.2016.07.001 煤沥青型焦制备与固结机理 杨永斌，钟强，姜涛，李骞，徐斌 ( 中南大学 资源加工与生物工程学院，湖南 长沙，410083) 摘要：以煤沥青为黏结剂，对焦粉型焦制备新工艺及其固结机理进行研究。研究结果表明：助剂 BJ 可激发煤沥 青中芳香烃等化合物的活性，使煤沥青常温下具有黏结性，实现型焦的冷压成型，其湿块 2 m 落下强度大于 50 次； 超细磨填充料可填充煤沥青收缩产生的孔隙，充实煤沥青炭化骨架，强化型焦的炭化固结；煤沥青最大的热分解 挥发速率和热缩聚速率分别出现在 336 ℃和 629 ℃，湿块经 370 ℃挥发 15 min 及 600 ℃炭化 30 min 后制备的型 焦抗压强度达 20 MPa ；煤沥青在挥发和炭化中解脱除H 和 N 等并吸收 O 缩聚形成 C—C 键的炭化骨架，其 C 与 H 的物质的量比由 1.69 提高至 2.80 ，C 与 O 的物质的量比由 91.77 降低至 67.23；型焦炭化块主要由 C 及少量 O 构成，煤沥青形成的 C—C 键炭化骨架将焦炭颗粒牢固地黏结成块，使得型焦内部结构紧密、均质性好。 关键词：煤沥青；型焦；炭化骨架；固结机理 中图分类号：TD984 文献标志码：A 文章编号：1672−7207(2016)07−2181−08 Preparation and mechanism of formed coke with coal tar pitch as binder YANG Yongbin, ZHONG Qiang, JIANG Tao, LI Qian, XU Bin (School of Minerals Processing and Bioengineering, Central South University, Changsha 410083, China) Abstract: Preparation and mechanism of formed coke with coal tar pitch as binder were studied. The results show that assistant reagent BJ can excite the activity of aromatic compounds of coal tar pitch and make coal tar pitch have the cold state cohesiveness, which realizes briquetting of coke breeze at room temperature without heating process. The drop resistance of the wet briquette is 50 times per 2 m. Filling material of ultrafine particle can fill the pore produced by shrinkage of coal tar pitch, enrich the skeleton of coal tar pi