钛酸盐纳米管降低卷烟烟气有害成分-烟草科技.PDF

烟草科技/TobaccoScienceTechnology 烟草化学/Tobacco Chemistry 2013年第 8期（总第313期） 钛酸盐纳米管降低卷烟烟气有害成分 邓其馨，黄朝章，张建平，吴清辉，叶仲力，许寒春，谢 卫* 福建中烟工业有限责任公司技术中心，福建省厦门市海沧区新阳路1号 361022 摘要：通过简单的水热反应法制备了一种可同时降低主流烟气中多种有害成分的钛酸盐纳米管。采用X 射线粉末衍射分析（XRD ）、扫描电子显微镜（SEM ）、透射电子显微镜（TEM ）和傅立叶变换红外光谱 （FT-IR ）对合成纳米管的结构进行了表征。结果表明：①在卷烟滤嘴中添加钛酸盐纳米管后，主流烟气中 的氨、氢氰酸、苯酚和巴豆醛等有害成分的释放量分别降低了67.53% ，23.52% ，60.81% 和27.56% ，其中，氨 和苯酚释放量的选择性降低率大于35% 。②钛酸盐纳米管对有害成分的吸附机理表现为物理吸附和化 学吸附的共同作用。 关键词：卷烟烟气；有害成分；纳米管；钛酸盐 中图分类号：TS411.2 文献标识码：A 文章编号：1002-0861 （2013 ）08-0037-04 ReducingHarmfulComponentsinCigaretteSmokewithTitanateNanotubes DENG Qixin, HUANG Chaozhang, ZHANG Jianping, WU Qinghui, YE Zhongli, XU Hanchun, and XIE Wei* Technology Center, China Tobacco Fujian Industrial Co., Ltd., Xiamen 361022, Fujian, China Abstract: Titanate nanotube, which could simultaneously remove multiple harmful compounds in mainstream cigarette smoke, was successfully synthesized by a simple hydrothermal process. The synthesized titanate nanotubes were characterized by XRD, SEM, TEM and FT-IR techniques. The results showed that: 1) When titanate nanotubes were added into cigarette filter, the deliveries of ammonia, hydrogen cyanide, phenol and crotonaldehyde in mainstream cigarette smoke reduced by 67.53%, 23.52%, 60.81% and 27.56%, respectively; and the selective reduction rates of ammonia and phenol were more than 35%. 2) The adsorption mechanism of titanate nanotube performing on harmful components presented a combined action of physical and chemical adsorption. Keywords: Cigarette smoke; Harmful component; Nanotube; Titanate ［2 ］ 卷烟烟气中的主要成分焦油和烟碱等对人体有害， 较严重的危害 。在滤嘴里添加材料选择性降低烟气 其中，焦油中的有害成分对人有致癌作用；烟碱易使人 中的有害成分是目前卷烟减害研究的重点之一。用于 ［1 ］ ［3 ］ 产生依赖性，还能麻痹呼吸中枢，引起心血管疾病