过渡金属磷化物的制备 表征和肼分解性能的研究-工业催化专业论文.docxVIP

Abs仃act Abs仃act Abstract Ruihua Cheng(Industrial Catalysis) Directed by Prof．Tan Zhang As a novel class of catalyst，transition metal phosphide has been explored and showed highly active for hydrodesulfurization(HDS)and hydrode- nitrogenation(HDN)，but few studies were reported in other eatalytic reactions． This thesis focused on the synthesis of MoP with high surface area and mghly dispersed MoP／A1203，as well as the characterization of active sites by microcalorimetry with CO as probe molecular．Decomposition of hydrazine Was also explored with these phosphides．and the decomposition mechanism was studied with in-situ FTIR． The high surface area of MoP Was prepared by the citric acid·temperature programmed reduction method．The decrease in agglomeration and the formation ofpores were responsible for the increase in the surface area ofMoE This method appeared to be a versatile method for producing high surface area transition metal phosphides and supported MoP／A1203 catalysts． Studies on the chemisorption of CO by microcalorimetry gave．some insights into the nature of active sites on MoP．CO Was primarily adsorbed at one MoP surface site，which had high differential energyfor both MoP prepared by the two methods．The hilgh surface area MoP had an increase in the number of active sites but there Was no change in the chemical nature of MoP． The decomposRion activity of hydrazine OVer a sedes of unsupported phosphides decreased as follow：MoP-WPCoPNi2E From the IR spectra,when N2I-14 Was adsorbed on MoP／A1203，there appeared a band at 1484 cml which was Abstractassigned Abstract assigned to NH4+．Hydrazine was found tO adsorb mainly on Mo site船revealed by c0-adsorption with CO and NzH4． Phosphide catalysts were found to be active and stable at room temperature． Microcalorimetric adsorption ofNH3 revealed that NH3 molecules were adsorbed more strongly on M02N than on MoP．The in-situ FTIR results of co-adsorption of CO and N2I-14 over MoP／A1203 and M02N／A1203 exhibited two distin