海水中农药的光化学降解研究-海洋化学专业论文.docxVIP

青岛海洋大掌硕士掌位论文d．Heavy 青岛海洋大掌硕士掌位论文 d．Heavy metal ions：in all reactions，different ions in different reaction systems play roles in different way．The influence resulted mainly fmm the interactions between ions and aquatic mediates． e．Photosensitizer：two photosensitizers have different effects on the reactions．In most reaction systems，they quicken the reaction steps． 2 Monocrotophos can not be photodegraded by the irradiation of high-pressure mercury lamp。but it will be quickly degraded if Ti02 is added as catalyst．The factors lhal w川influence lhe photodegradation are： a．Aquatic mediates：Che reaction in de-ionized water iS fastesf while it seems a bil faster in preparing seawater lhan that in naturaI seawater． b．AmounI of TiO。：lhe optimum iS 4．0-5．09／L． c．MetaIIons：lrace Cu2+and FeZhNill accelerate the degradation in H。0 solution． d．Photosensitizer：two photosensitizers have no effects on the reactions． e．Degradation resultants：medium and finaI resultants are detected．including methanoic acid，acetic acid and 3一methyl-phosphate as medium．As finaI resultants，organic phosphorus will be transferred into POP． In brief．for the two organic pollutants in seawater，a series of results have been obtained in the respects of photochemical degradation，photocatalytic degradation， kinetic behavior and their influencing factors．Based on the experimental results in this thesis，we can have the further understanding on the photodegradation situations of organic substances in marine environment． Keywords Penfachforophenof，Monocrotophos，Photochemical Degradation。Photocatalytic Degradation，Kinetics，Seawater 海水中农药的光化掌降解研究一、引 海水中农药的光化掌降解研究 一、引 言 海洋有机光化学是一门新兴的海洋学科，其重要性正在受到各国 研究人员的重视。海水中的许多物质在海洋表层都能够吸收阳光的辐 射，发生各种物理和化学变化，从而改变它们原有的结构、组成、含 量、分布及相互作用等，并在海洋中元素的循环、物质的迁移变化和 海洋生物的活动等方面产生重要影响。作为海洋化学的一个重要研究 分支，海洋有机光化学与其它海洋学科，如海洋环境、海洋地球化学、 海洋生物等密切相关，在整个海洋学研究领域内具有重要地位。 1．1海洋有机光化学的国内外研究现状 早在1912年，光化学家Giacomo Cismician就提出了光化学具有 巨大发展潜力和应用价值的观点[1]。进入二十世纪六十年代，海洋光 化学方面的研究才逐渐开展，而且在发展初期，研究内容仅限于对海 洋光化学的初步认识，多数研究