毕业论文-酸液稠化剂的制备与性能评价.docVIP

PAGE 本科毕业论文 （20 届） 酸液稠化剂的制备与性能评价 专业：高分子材料与工程 摘 要：酸化处理是油气井增产的重要措施之一，而稠化剂是酸液中一种重要的酸性添加剂。文中以二甲基二烯丙基氯化铵和丙烯酰胺为原料，过硫酸铵-亚硫酸氢钠为引发剂制备酸液稠化剂PDA。实验考察了单体配比、反应温度和引发剂用量等反应条件对共聚物特性粘数的影响。采用行业标准（SY/T6214-1996）对聚合物性能进行了评价。结果表明：PDA最优合成工艺为单体配比n(AM):n(DMDAAC)=6:1，低温和高温反应适宜温度分别为15，60℃，引发剂用量为占单体总质量的0.1%。该条件合成的PDA的粘均分子量200万以上。 关键词：稠化剂；二甲基二烯丙基氯化铵；丙烯酰胺；合成；结果 Synthesis of Acid Thickening Agent and Properties Evaluation Abstract：Acidification is one of the important measures in gas and oil reservoirs, and the viscosifier is an important acid additive. In this paper, dimethyl-diallyl-ammonium chloride(DMDAAC) and acrylamide(AM) are used for material. Ammonium persulfate and sodium bisulfite are used as initiator. The experiment investigates the effects of monomer ratio, reaction temperature and initiator concentration of reaction conditions on intrinsic viscosity of copolymer. Using the industry standard (SY/T6214-1996) evaluated the performance of polymer. The result shows that: the optimal synthetic process for PDA monomer ratio n (AM): n (DMDAAC) = 6:1, and low and high temperature reaction 15,60℃respectively appropriate temperature, and the initiator concentration is respectively 0.1% of the total monomer. This condition synthesis of the PDA are molecular weight more than 2 million sticking. Key words：viscosifier; dimethyl-diallyl-ammonium chloride; acrylamide; synthesis; result PAGE 2 目 录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc292717982 1前言 PAGEREF _Toc292717982 \h 1 HYPERLINK \l _Toc292717983 1.1酸化的概述 PAGEREF _Toc292717983 \h 1 HYPERLINK \l _Toc292717984 1.2酸化处理的发展史 PAGEREF _Toc292717984 \h 1 HYPERLINK \l _Toc292717985 1.3酸液添加剂 PAGEREF _Toc292717985 \h 2 HYPERLINK \l _Toc292717986 1.4酸液稠化剂的应用现状 PAGEREF _Toc292717986 \h 3 HYPERLINK \l _Toc292717987 1.5酸液稠化剂PDA的性质、结构 PAGEREF _Toc292717987 \h 3 HYPERLINK \l _Toc292717988 1.5.1 PDA的性质 PAGEREF _Toc292717988 \h 3 HYPERLINK \l _Toc292717989 1.5.2 PDA的结构 PAGEREF _Toc292717989 \h 3 HYPERLINK \l _Toc292717990 1.6本文研究的意义 PA