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2013年4 月 Vol.31No.4
April2013 ChineseJournal of Chromatography 335~341
Special column of chromatographic stationary phases:Articles DOI:10.3724/ SP.J.1123.2012.11016
Sub ̄micrometer mesoporous SBA ̄15 silica rods as stationary
phase for capillary electrochromatography separation
ZHANG LingyiꎬWANG ZhicongꎬZHANG Weibing∗
(ShanghaiKeyLaboratory of FunctionalMaterials ChemistryꎬEast China University of
Science and TechnologyꎬShanghai200237ꎬChina)
Abstract:Mesoporous SBA ̄15 silica rods were packed into capillary as stationary phase for capillary electro ̄
chromatography (CEC) separation. Theattractiveproperties ofthesub ̄micrometermaterial areitsradical size
of400 nm and highly ordered cylindrical mesopores running along the same direction. The special structure is
formed by pilingofrodshapeparticlesꎬwhichprovidegoodpermeabilityandfacilitatethepackingprocedureof
small sizeCECcolumn. Themodifiedsilicaparticlesweresuccessfullyappliedforthereversed ̄phase (RP)and
ion ̄exchange (IE) electrochromatographic separation of non ̄polar andpolar compoundswith satisfactory effi ̄
ciency (140000 plates/ m for benzene using 70% (v/ v) acetonitrile). The van Deemter plot showed the hin ̄
dranceto mass transfer because of the existence of pore structure. The lowest plate height of 71 mm was
obtainedatthelinearvelocity of32 cm/ min. Thepreparedion exchangecolumnwasappliedtotheseparation
of Chinesetraditional medicines Ginseng andRhizoma Gastrodiae.
Key words:capillary electrochromatography (CEC)ꎻsub ̄micrometerꎻSBA ̄15 silica rodsꎻstationary phase
CLC number:O658 Document code:A Article IC:1000 ̄8713(2013)04 ̄0335 ̄07
亚微米中孔SBA ̄15棒状固定相在毛细管电色谱分离中的应用
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