超亚临界水两步法水解稻秆制备还原糖-生物质化学工程.PDFVIP

第45卷第4期 生摇 物摇 质摇 化摇 学摇 工摇 程 Vol.45 No.4 2011年7月 Biomass Chemical Engineering July2011 ·研究报告———生物质化学品· 超/ 亚临界水两步法水解稻秆制备还原糖 刘慧屏,徐 刚,罗鹏,银建中* (大连理工大学化工机械学院, 辽宁 大连 116024) 摘摇 要:以稻秆为原料,采用两种间歇式反应工艺,对其在超/ 亚临界水条件下两步水解过程进行研究。 重点考察反应温 度、反应时间、液固比对水解行为的影响,并与超临界一步法水解工艺进行了比较。 结果表明,对稻秆进行低温段水解, 液固比100 颐1,190 益、40min条件下最大还原糖得率21%,将液固比降低到40 颐1,20min 即可获得与液固比100 颐1时 40min反应相当的还原糖得率。 将低温段水解残渣作为高温段第二步水解的原料,在380 益、20s条件下获得最大还原 糖得率为57%,超/ 亚临界两步法水解稻秆工艺所获得的总还原糖得率为45%。 相同条件下,用超临界一步法直接对 稻秆进行水解,40s时获得还原糖得率最大,为32%。 超/ 亚临界水条件下两步水解比一步法水解工艺的还原糖得率提 高了13 个百分点。 关键词:生物质;稻秆;超/ 亚临界水;水解;还原糖 中图分类号:TQ352摇 摇 摇 摇 摇 摇 摇 文献标识码:A摇 摇 摇 摇 摇 摇 摇 文章编号:1673-5854(2011)04-0017-06 Reducing Sugars Production from Rice Straw by a Two鄄step Hydrolysis with Supercritical/ Subcritical Water LIU Hui鄄ping,XU Gang,LUO Peng,YINJian鄄zhong (School of Chemical Machinery,Dalian University of Technology,Dalian 116024,China) Abstract:Reducing sugars can be derivedfrombiomassviahydrolysisprocess. Atwo鄄stephydrolysiswith supercritical/ subcritical water were appliedfor rice straw hydrolysis. The effectsof keyfactorsastheratioof liquidphasetosolidphase,reactiontemperature and time on the yield of reducing sugarswere evaluated. The relationship of rice straw liquefaction rate vs. ratio of liquid phase to solid phasewere investigated. Rice鄄straw were hydrolyzed using a two鄄step hydrolysis processwith subcritical water combined with supercritical water and one鄄step supercritical water hydrolysis process respectively. The maximum yield of reducing sugars was about21% at 190 益 for40 minwhentheratioof liquidphaseto solidphaseof the substrateswas 100 颐1,whiletreatingthe rice straw using the two鄄step process. Meanwhile,the sameyieldof reducing sugarswereobtainedwhenthera