氯仿萃取法消除氰化物测定中的油干扰-工业水处理杂志.PDF

2001 年1 月 Jan.,2001 第21 卷第1 期　　　　　　　　　　Industrial Water Treatment 　　　　　　　　　　　V l.2 1 N .1 李广志 (丹徒县环境监测站, 江苏 镇江　2 1200 1) 　　[] 、、, , , NaOH , , 。, , , , 、, 。 　　[] ;; 　　[] T U991.2 1　[] A 　[] 1005-829X(200 1)01-0037-02 Eliminat ion of grease disturbance in cyanide determinat ion by chloroform extraction LI Guang-zhi (D an t u E nv ironment al M oni tor ing S tat ion , Zhenj iang 212001, Ch ina ) Abst ract :The w astew ater fr m gum benzi n pr ducti n c ntains benzaldehyde, cyanide, gum benz in and ethyl benz ate.When the cy anide is determined by is -nic tinic acid-pyrazal n meth d, the ethyl benz ate is distilled and g es int NaOH abs rpti n liquid w ith cy anide in the pr cess f pre-distillati n, because its b iling p int is l w .Thus the abs rpti n liquid pr duces a great deal f f am and feculence.This disturbs the sequent c l rimet- ric determinati n seri usly.T separate the grease and w ater, chl r f rm extracti n is used t rem ve the grease.Then the cyanide in w ater can be determined.Experiments sh w that this meth d has ideal unanimity, less err rs, and high recurrence rate.It is an effective w ay t eliminate rganic grease disturbance. Key words:chl r f rm;extracti n;cyanide determinati n;grease disturbance 　　《》, , , COD , Cr , 3 。61.7 ℃、1.483 2 g/cm , EDTANa , EDTANa 2 2 ,, ,, 。, NaOH 。, , , , ,, , , ,, , 。 ,, 1　 、、,