光声光谱技术中的多气体成份分析方法研究-光学工程专业论文.docxVIP

摘要激光腔内光声光谱测量是一种高灵敏度的微量气体检测方法，采用多条激光 摘要 激光腔内光声光谱测量是一种高灵敏度的微量气体检测方法，采用多条激光 谱线测量能同时对多种微量气体浓度进行定量分析。这种方法广泛应用于大气污 染检测和生物代谢气体分析。 本论文首先介绍了光声技术的发展和现状，详细讨论了c0。气体存在情况下 多成份混合气体光声光谱理论以及与之相对应的数据处理算法，同时介绍了光声 光谱系统的结构和控制软件的编写思想。 由于受c02与N。分子之间传能引起的动力学冷却效应的影响，在混合气体中 含有CO,时，光声信号的幅度与气体的浓度不再呈线性变化，位相也发生变化。 选择线性拟合的数据处理方式不能得到正确的分析结果。而采用非线性 Levenberg—Marquardt拟合方法处理实验数据，能够有效的消除混合气体中c0。 气体对其他气体浓度检测结果的影响。 利用基于波导cO。激光腔内光声光谱仪，对大气污染气体和生物代谢气体成 功进行了分析。通过对cO：浓度变化的混合气体中恒定c。巩的检测，显示了线性 方法的局限性，同时证明了L—M非线性算法的正确性。采用L州数据处理方法， 正确得到富士苹果释放的c。H。含量和混有摩托车尾气的空气中的c。fL浓度，以及 复印室空气中的c。m和O。浓度，实验结果验证了非线性拟合分析方法的有效性。 关键词： 光声光谱仪：微量气体；动力学冷却效应；非线性拟合 AbstractC02 Abstract C02 laser basedintraeavity photoacousic spectroscopy is high sensitive method for monitoring trace gases．The concentrations of different gases in multi—component gas mixture could be quantitatively determined respectively with multi—line detection technique．This technique have been widely used in the research of air pollution and metabolic process of biology trace gas detecting t001． The history and recent development of photoacoutic technology firstly introduced in this paper．Then，the photoacoustic theory of multi-component gas detection and data processing algorithm are discussed in detail．The system’S scheme mad controlling program are also presented． Due to the effect of dynamic cooling caused by energy exchange between C02 and N2 molecules，the PAs amplitude has linear relation with gas concentrations， and the phase also changes．The linear solution of multi—line detection scheme might lead outcome when the gas mixture contains C02．So the Levenberg—Marquardt algorithm for fitting nonlinear functions is applied to calculating the concentrations ofmulti—component gas mixture containing C02 gas． A waveguide C02 laser based intracavity photoacoustic spectrometer is successfully applied to analyzing the trace gas samples of polluting air and biological metabolism．The experimental results of gas mixture with constant C2t-h concentration and changing C02 con