光催化净化室内空气中甲醛的研究-环境工程专业论文.docxVIP

塑主堡兰 塑主堡兰 堂堡些堡垡皇由皇兰!!鳖塑翌塑——— Y 624 706 摘要 以钛酸丁酯[Ti(OBu)41为原料，用溶胶一凝胶法在玻璃纤维却上负载Ti02催化剂， 进行光催化氧化甲醛气体的实验研究。实验中用XRD方法对所制备的Ti02粉末进行 表征，结果表明所制备的Ti02粉末晶型为锐钛矿型，粒径在9 nm～ll nm之间。在 进口气体流量为20 L／h、甲醛浓度为168 u g／L，面积为158．4 c,m2的玻璃纤维布上Ti02 的负载量从0增加至O．32 g的条件下，甲醛气体净化率随Ti02的负载量的增加而逐 渐增大，最大值可达到87．O‰当负载量继续增加时，净化率基本保持不变。光催化 反应器中，甲醛气体净化率随气体有效停留时间的增加而提高，当气体有效停留时间 从11．9 s增至23．8 s时，达到最大值87．O％，随后趋于平缓。当掺杂Fe”量由O增加 至0．2％时，甲醛气体净化率可由87．0％增至95．2％，掺杂Fe计通过降低光生电子和空 穴复合率提高了Ti02光催化活性。Langmuir．Hinshewood方程适用于光催化氧化甲醛 的反应过程，推导出的数学模型的计算值与实验值较好吻合。 关键词：光催化氧化，甲醛，二氧化钛，溶胶一凝胶法，掺杂，动力学 硕士论文 硕士论文 光催化净化室内空气中甲醛的研究 Abstract In the experiment，using tetrabutylorthotitanate【Ti(OBu)4】as the precursor，the Ti02 was supported on the glass fibers by the sol—gel method and then was used as the catalysts to photocatalytic oxidation of the gaseous formMdehyde．The Ti02 powder that was prepared by the sol—gel method in the experiment was analyzed by the XRD method．The results showed that the crystalline phase of Ti02 was anatase and the crystal size of Ti02 rmlge from 9nm to 1 lnm．When the gas flow rate was 20L／h and the concentration of gaseous fomlaldehyde was 168 u g，L，the quality ofTi02 supported on the glass fibers which area was 1 58．4 cm2 was increased from 0 to 0．32 g．SO the percentage of degrading gaseoUS formaldehyde increased with the increase of quality of Ti02，and the best efficiency、~ras 87．O％．When the quality of Ti02 kept increasing，the efficiency maintained the constant． When the effectual reaction time in the photoreactor increased，the percentage of degrading gaseous formaldehyde increased．When the effectual reaction time increased from 1 1 9 S to 23．8 S，the efficiency can arrive at 87．O％，and then the efficiency maintained the constant When the concentration of Fe”doped in Ti02 increased from 0 to 0．2％，the efficiency increased from 87．O％to 95．2％．The reason was that the Fe”doped in Ti01 carl decrease the percent of photogenerated electron reuniting with photogene