含氟烷基多元羧酸的合成及其在织物整理中的应用-应用化学专业论文.docx

含氟靛基多元羧酸的合成及其在织物整理牵的威用摘要 含氟靛基多元羧酸的合成及其在织物整理牵的威用 摘要 絷整瑟麓靛瑟整是提商统绞魏晶最的重蘩落素，因既，我稍设计 并合成了一类新型多功能目标分子，期望该分子能够赋予织物拒水、 拒滴、防污以及抗皱功能。 该目标分子的结构特点是：分子结构中尉对存褒全氟烷基和多元 羧酸交联基闭。 ， 该嚣拣分子豹含残过摇楚这样移；誊先将舞二酸二乙黪与溪乙羧 乙酯进行烷基化反应，制得的产物再与烯丙綦溴反臌，该两步反成均 采瘸忑撬碱军毽耱转移催亿裁体系，反应条俘滠器，产率努巅兔82％和 97％；第三步，在保险粉(Na。S。0。)引发下，将制得的三羧黢三乙酯2 与含，℃个碳的全氟烷基碘反应，得蓟含氟烷基三羧酸酯3，产率71％： 最后，将含氟烷基三羧酸龋3东碱性条件下水鳞制褥含氟烷基三羧酸 4。 我{|、]将疆标分予对擦织麴的整理避嚣了礤究，绥果表明，该毯蠡 分子能够赋予织物拒水、拒油、防污以及抗皱性能。由于目标分予中 戆三今羧基与织貉绎维素发生醭交联豫震，使经该韵裁整臻过酶绞物 的整理效果舆有～定的耐久性。 关键词；含氟烷基，多元羧酸，多功能攘理，光甲酸抗皱熬理 Synthesis Synthesis of Perfluoroalkyl*containing Polycarboxylic Acid and Its Application in Textile Finishing Abstraet As quality dyeing and finishing agents are the key to improve the fabric quality standards，a new type of multifunctional molecular was designed and synthesized。It possessed water repellency，oil repellency， soil repelIency and wrinkle resistance for textile finishing． This molecular contains both perfiuoroalkyl ehain and polycarboxylic acid cross-linking groups． The molecular Was synthesized via alkylations of diethyl malonate with ethyl bromoacetate and allyl bromide，under modified anhydrous conditions with base and phase transfer catalyst。The yields were 82％ and 97％respectively．The resulting triethyl tricarboxylate 2 was reacted with iodoperfluorooctane initiated by sodium dithionite to afford peffluofoalkyl毪te矗trieafboxy|at嚣3 in 7 1％yield。Then，hydrolysis of perfluoroalkylated tricarboxylate 3 under base conditions to give the peffluQ}oa攮yla{ed tricarboxylic acid 4。 The application of this target molecular On cotton showed that it can provide water repellency,oil repellency，soil repetlency and wrinkle resistance to textiles．Due to three earboxylic groups within the molecu lar，this reagent can provide good durabilities after textile finishing。owing to the cross—linking between multi*earboxytie groups and cellulose， Donghuanwen(Applied Chemistry) Directed by professor Fengling·Qing Keywords： Keywords： perfIuoroalkyl-containing， polycarbOxyIic acid， multifunet