精馏与盐效萃取偶合过程-高校化学工程学报.PDF

19 5 No.5 Vol.19 2005 10 Journal of Chemical Engineering of Chinese Universities Oct. 2005 1003-9015(2005)05-0598-05 1 1 2 , , (1. , 210096 2. , 300072) TQ028.8 A The Separation Process of Distillation Coupled with Salt Extraction 1 1 2 PAN Xiao-mei , XIAO Guo-ming , YANG Zhi-cai (1. Department of Chemistry and Chemical Engineering , Southeastern University, Nanjing 210096, China; 2. Institue of Chemical Engineering, Tianjin University, Tianjin 300072, China) Abstract: A novel process combining batch distillation and salt extraction was proposed to separate the organic solvents from their azeotropes with water. A salt extractor installed on the top of the distillation tower could remove most of water in the azeotrope evaporated from top of tower, and a middle vessel was installed at the middle of the tower to separate water from bottom of the tower. Since the water can be drained off both from bottom and top of the tower at the same time, and finally the organic solvent is concentrated in the tower and accumulated in the middle vessel, therefore the process is time-shortening and energy-saving one. The concentration of the product may be up to 99.8% and the product yield may reach 99.5%. The experimental study and mathematic simulation were carried out and agree with each other quite well. Key words: salt effect; salt separation; salt extraction; azeotropes; acetonitrile 1