混凝土界面过渡区的特点与碱硅酸反应的关系-结构工程专业论文.docxVIP

混凝土界面过渡区的特点与碱硅酸反应的关系摘 混凝土界面过渡区的特点与碱硅酸反应的关系 摘 要 碱硅酸反应是影响混凝土耐久性重要因素之一，而界面过渡区又是混凝土 的薄弱环节。通过界面过渡区来研究混凝土的碱硅酸反应，对解决混凝土耐久 性这一难题具有重大的意义。 本文采用活性骨料沸石化珍珠岩和外掺不同的碱、盐来成型混凝土试样，研 究了潜在碱硅酸环境下的界面过渡区的形貌特征。利用原子吸收光谱仪和比长 仪分别测试了潜在的ASR混凝土中的孔溶液和砂浆棒膨胀性能；通过它们之间 的内在联系，揭示了界面过渡区与碱硅酸反应的关系；并从界面过渡区的特征 对ASR抑制机理方面进行了的探讨。 实验表明潜在碱硅酸反应的界面过渡区具有以下特点：界面过渡区的整体 结构较为疏松多孔，微裂缝较多； CH晶体和钙矾石较多；钙矾石以网状的形 式分布在过渡区并且骨料附近凝胶相对较少；在碱含量较高的情况下，界面过 渡区会出现碱晶体。碱、盐的掺入，提高了孔溶液中金属阳离子、OH。和S04z。 浓度；并随着掺入碱、盐量的增加，碱硅酸反应膨胀越强烈。当在潜在的ASR 混凝土掺入活性掺合料时，界面过渡区中产生一些新的凝胶(如C．A．S．H)；这 些新的凝胶包裹在CH表面。锂盐的掺入使得潜在的混凝土界面过渡区中产生 大量的凝胶，同时界面过渡区中CH会大量减少。无论加入活性掺合料还是锂 盐，碱硅酸反应都能得到有效的抑制。 研究表明，碱硅酸反应强度的大小与孔溶液中的碱离子有着密切的联系， 而界面过渡区的组成与结构，又对孔溶液的离子变化起着决定性的作用。 关键词：界面过渡区，碱硅酸反应，孔溶液，混凝土 On On the Relationship between Interfacial Transition Zone and Alkali．Silica Reaction ABSTRACT Alkali-silica reaction is an important factor affecting the durability of concrete，while the interfacial transition zone(ITZ)is the weakest in concrete．It is necessary to investigate the alkali—silica reaction of concrete from the viewpoint of ITZ． In this thesis，concrete specimen，with high activity of zeolite-base perlite as aggregate，mixed with different alkali and salt，were molded．The performance of pore solution and mortar bar were tested by atomic absorption spectrometry and Comparator．The mechanisms of admixtures for inhibiting ASR were analyzed by observing the characteristics of ITZ． The results showed that ITZ in ASR potential concrete characterized in more pores，micro-cracks，CH crystals and ettringites and little C-S-H gel．The ettringites net-like distribute in the ITZ．Alkali crystalled in the ITZ of the specimen mixed with high content of alkali．The more the alkali and salt mixed in concrete，the more R+，OH。and S04厶existed in pore solution．With the increase of incorporated alkali or salt，the expansion of ASR were more apparent．As the ASR potential concrete mixed with active mineral materials，new gel(such as CASH)，generally wrapped in CH surface．，formed in the ITZ．In ITZ with lithium salt addi