几种LED用氧化物基荧光粉的制备和发光性能研究-材料科学与工程 材料物理与化学专业论文.docx

兰州大学博士论文Abstract 兰州大学博士论文 Abstract White light·-emitting diodes(LEDs)technique is all important kind of solid··state illumination．In comparison谢m conventional incandescent and fluorescent lamps， the white LEDs show many advantages such as high luminescent efficiency，long lifetime，environment friendly，which promise significant reductions in power consumption in the 21st century．In the case of lighting，white light can be generated by several different methods．The most commonly method is to combine a phosphor with a GaN LED chip，and this is called as phosphor-conversion method．So the phosphor conversion LEDs light strongly depends 011 the phosphor whether it Can be efficiently excited by blue or UV emission of LEDs chip or not．Now,there are two major problems 011 the development of phosphors：one is that the yellow phosphor used in blue LEDs has relatively weak emission in the red spectral region，resulting in inaccurate color rendition；the other is that the tricolor phosphors used in UV LEDs have a low emission intensity，resulting in a low luminous efficiency．Therefore，it is a significant work to seek a kind of phosphor丽t11 lligh luminous efficiency and better color reproducibility for blue or UV LEDs． The red phosphors CaS004[Eu3+,M(M=Si，Nb，V，Sr，Tb，Pb，ete)were synthesized by solid state reaction．We firstly found that the red emission intensity of the phosphor CaM004：Eu3+Was seriously enhanced when M06+Was replaced by Si4+or Nb5+．The optimize emission intensity of Si and Nb co-doping samples is as 5．5 and 4 times high as that of Y202S：O．05Eus+,respectively．In addition，because NaEu(i004)2 and CaM004 have similar structures，the red phosphors NaEu(M01．嚣Mx002(M=Si,Nb) were also synthesized by solid state reaction．The optimize emission intensity of NaEu(Mol-xSix04)2 and NaEu(Mol-xNbx04)2 samples reached as 3．8 and 3 times as that ofY202S：0．05Eu计，respectively．It indicated that the two modified red phosphors might be more suitable for the UV-LED than the sulfide phosphor