几类苯并杂环化合物二阶nlo和荧光性质的研究-物理化学专业论文.docxVIP

ABSTRACTIn ABSTRACT In this thesis，the molecular second—order nonlinear optical(NLO)properties of several kinds of benzo—heterocycle compounds and some disubstituted D川。一A organic chromophores with long conjugated chain were studied And the fluorescence properties of some benzo—heterocycle compound solutions were also investigated The context WaS divided into 3 chapters as below． Chapter 1：Introduced briefly the nonlinear optiCS，the theory and the development of organic second—order NLO materials，as well as the basic principles and the research of fluorescence，the factors that affect fluorescent properties of fluorescent materials were also discussed． Chapter 2：The microscopic second-order NLO properties of 2,4一(1 H．3H) QuinazoIinedIones and disubstituted D-丌-A organic chremophores were systematically studied．The relationship between substituents，substituted position，the extension ofTTconjugated system，planadty of molecules and molecular hyperpOIar泣abiIi戗es were obtained based on the theoretical calculations to design and synthesize excellent organic second—order NLO materials． Chapter 3：A group of pyrido[1．2-elpurin-4(3H)-one and benzimidazole derivatives were synthesized．The fluorescent spectroscopy tests of the solutions of these compounds were carried out and then were the analysis of their properties． Quantum Yields of the compounds were calculated．The effects of the molecular structures of the compounds，the substituents and the solvent on the fluorescent properties of these compounds were also discussed． Keywords：Second Order Nonlinear Optics Fluorescent Properties ab initio Calculation Benzo-heterocycle Compounds II 学位论文独创性声明 学位论文独创性声明 本人郑重声明： 1、坚持以“求实、创新”的科学精神从事研究工作。 2、本论文是我个人在导师指导下进行的研究工作和取得的研究 成果。 3、本论文中除引文外，所有实验、数据和有关材料均是真实的。 4、本论文中除引文和致谢的内容外，不包含其他人或其它机构 已经发表或撰写过的研究成果。 5、其他同志对本研究所做的贡献均已在论文中作了声明并表示 了谢意。 作者签名：立竭：i近 日 期：盘鲤‘．』。置： 学位论文使用授权声明 本人完全了解南京师范大学有关保留、使用学位论文的规定，学 校有权保留学位论文并向国家主管部门或其指定机构送交论文的电 子版和纸质版；有权将学位论文用于非赢利目的的少量复制并允许论 文进入学校图书