乳化工艺对高粘度硅油乳液粒径及分布的影响.docx

乳化工艺对高粘度硅油乳液粒径及分布的影响 王春焱， 安秋凤 （陕西科技大学轻化工助剂化学与技术教育部重点实验室， 陕西西安 710021） 摘 要： 以粘度为 2 000 Pa·s 的α,ω-二羟基聚二甲基硅氧烷和十六烷基改性硅油(CMSO)为原料,非离子复配表面活性剂为 乳化剂,采用机械乳化法制备小粒径高粘度硅油乳液,分析了乳化剂和十六烷基改性硅油用量、乳化方法、乳化时间以及搅拌速度对 乳液粒径及分布的影响.结果表明,当 CMSO 用量为 30%,乳化剂用量为 10%,乳化时间为 50 min,搅拌速度为 1 500 r/min 时,高剪切正相 法制得乳白色至蓝白色高粘度硅油乳液,含固量为 30%、平均粒径 D为 257.7 nm. 关键词： 高粘度硅油; 硅油乳液; 乳液粒径; 乳化工艺; 粒径分布 中图分类号: TQ314.24 文献标识码: A 文章编号: 1004-0439(2014)01-0013-04 Effect of emulsification process on the particle diameter and distribution of high-viscosity silicone oil emulsion WANG Chun?yan, AN Qiu?feng (Key Laboratory of Auxiliary Chemistry and Technology for Chemical Industry, Ministry of Education, Shaanxi University of Science Technology, Xi′an 710021, China) Abstract: The emulsion of high- viscosity silicone oil with small particle diameter was successively pre? pared using α,ω-dihydroxy poly(dimethyl siloxane) with viscosity of 2 000 Pa· s and cetyl-modified silicone oil (CMSO) as raw materials and compound of the non- ionic surfactant as the emulsifier through mechanical emulsification method. The effects of the amounts of emulsifier and CMSO, emulsifying method, emulsifica? tion time and stirring speed on the particle diameter and distribution of the prepared emulsion were dis? cussed. The results showed that the average particle diameter (D50) of prepared high viscosity silicone oil with milky white to blue white color using high shear normal phase method was 257.7 nm, and the percent of solid content was 30% when CMSO amount was 30%, emulsifier amount was 10%, emulsification time was 50 min and stirring speed was 1 500 r/min. Key words: high- viscosity silicone oil; silicone oil emulsion; emulsion particle diameter; emulsification process; particle diameter distribution 高粘度硅油是半无机半有机结构的高分子聚合 物,因具有优良的柔软性、疏水性以及湿润性已成为 日用化工、纺织工业以及皮革护理等领域的重要助 剂.但其强疏水性和油粘性导致乳化困难,严重制约 其性能的充分发挥,为此,研制高稳定性的小粒径高 粘度硅油乳液受到广泛关注. 有机硅乳液的制备方法有机械乳化法和乳液聚 合法.1959 年,美国道康宁公司的 Hyd