季铵盐型酸化缓蚀剂的研究-油气田开发工程专业论文.docxVIP

季铵盐型酸化缓蚀剂的研究 季铵盐型酸化缓蚀剂的研究 刘静静(油气田开发工程) 指导教师：张贵才(教授) 葛际江(副教授) 摘要 酸化是油’e片增产的一J负有效措施。为了防JL酸液对会膳设备和管什 的脶蚀，酸化时必须在酸液中加入一定莹缓蚀剂。 以甲醛、苯胺、环己酮、氯化苄和丙炔醇为原料，合成了一种新型曼 尼希碱。实验结果表明，90C时，20％HCI中添加l％的新型曼尼希碱， 可使豫液对NS0铜的腐蚀速率由2026，88晷／(m2·h)降到4．76姒m2·h)：120。C 时，2006Hcl添加2％的新犁曼尼希碱，br使腐蚀速幸降到14．30幽m2·h)。 由Tafel曲线可知，该缓蚀剂足一种混合型缓蚀剂，缓蚀机理属于几何覆 盖效应，在铁表面的吸附符合I．angmuir吸附等温式；阻抗分析表明，其等 效电路幽为Rs(RC)型，Nyquist图是一个处于第一象限的’#尉，缓蚀制 浓胜越大。容执弧越大。 为探讨杂环季铵盐缓蚀性能与结构的关系，以喹啉为原料，分别和氯 丙烯、环氧氯丙烷、氯化苄反应，合成了三种季铵盐，并将三种季铵盐与 丙炔醇和曼尼希碱进行了复配。评价结果表明，管荩氯化唪啉的缓蚀效粜 最好。i元复配体系相对于j元体系柬说，腐蚀速事有所下降。 关键词：酸化缓蚀剂，曼尼希碱，缓蚀机理，喹啉季铵盐 H Research Research of Quaternary Ammonium Salt Corrosion Inhibitor for Acidizing LIU Jing-jing(OilGas Field Development Engineering) Directed by Professor ZHANG Gui-cai andAssociate Professor GE Ji-jiang Abstraet It is an effective measure of increasing production in the oil gas well by using acidizing treatment．lb prevent the corrosion of metal from acidizing fluid，a certain amount ofcorrosion inhibitors must be put into the fluid． A new Mannich base was synthesized by cyclohexanone，formaldehyde， aniline，benzyl chlorine and propargyl alcoh01．At 90℃and 1 20℃the 。u“u。：uIl i“。uf B心hL：xtmc。出1 Ilh．a3urc up G¨f：bI dcgrcc ui’the st,mdald Jor add corrosion iahibitor，．TIle research of corrosion mechanism reflects that it belongs to the mixed corrosion inhibitor．Its absorption on the steel surface conforms to Langmuir absorption at constant temperature formula．The EIS shows that its equivalent electric circuit belongs to Rs(RC)，the capacitive lCdctdncc Arc increases along with the increase of corrosion inhibitor concentration． For probe into the relation between performance and structure，three quaternary ammonium compounds were synthesized．then mixed themⅥith ．＼lam：idl base and propArg)1 alcoh01．Thc results showed that the compound reacted by quinoline and benzyl chlorine Was the best one． Keywords：Acidizing corrosion inhibitor,Maanich base，Corrosion mechanism， Quaternary ammonium compound I| 独创性声明本人声明所呈交的论文是我个人在导师指导下进行