茴香脑间接电化学氧化合成茴香醛的研究-有机化学专业论文.docxVIP

ABSTRACTne ABSTRACT ne indirect electrochemical oxidation ofanethole to aJlisaldehyde with Ce4+／Ce3+as redox mediator System was studied in tms mesis．The electrochemical and chemical st印s were inVestigated sepamtely in order to detennine operating conditions pn)viding a high current e行iciency and high yield． 111e elec廿oche枷cal behavior of ce4+／ce3+in sul缸ic acid on platinum elec仃ode was investigated with conventional ways，such as linear sweep polarization and cyclic voltammogram，etc．The results of experiments show that the elecn‘ode reaction is conⅡD11ed by mixing pmcess of dimsion and charge—tranfer’and the eIec仃ochemical reaction ofCe4+／Ce3+ on platinum electrode is quaSi reVersible． 111e elec仃ocheInical oxida“on experiments of Ce”were perf‘ornled in a sin91e chamber cell，and the optjmum condiIions are as f01low：a platinum plate as anode and a stainless steel plate as cathode in the electr01yte s01ution containing 1 mol·L一1 H2S04+O．15 mol·L一1 Ce2(S04)3 through the electro．quantity of 1．5 F·m01-。using the current density of 1 4 mA·cm‘2 and the area ratio of cathode to anode 1：6 at the temperature of 30℃．Under this optimum conditions the electr01”ic yield of Ce4+is 88％ and the current emcient of 59％is o btained using galvanostatic mode After the regeneration cycle use of the redox mediator for 1 O times the electrolytic yield of 87％for the oxidation of Ce“can still be obtained． The o ptimization o f anisaldehyde s ynthesis c onditions w as c arried out by reViewing the effects of factors on the yield of anisaldehyde through through orthogonal tests and sin91e—f．actor tests．The optj mized result is the synthesis operation in 0．5 m01I。。1 sul凡nc acid solution in which ratio between Ce4+and aneth01e is 3：1 at the temperature of 30℃in the presence of benzene．Under the optimum conditions，the yield of reaction reaches 90％． In addition， the kinetics on the oxidation reaction of anetho】e to anisaldehyde by Ceric Sulfate was studied．The rate constants of aneth01e oxidation t