微波固相法制备CuZSM-5催化剂和其催化性能.PDFVIP

24 1 () Vol. 24 No. 1 2010 3 Journal ofUn iversit of South China( Science and T echnolog ) M ar. 20 10 : 1673- 0062( 20 10) 01- 0064- 06 微波固相法制备 Cu/ ZSM - 5催化剂及其催化性能 1, 2 1 阳鹏飞 , 周继承, 任文明 ( 1. , 421001; 2. / 0 , 411105) : 采用微波固相法和离子交换法制备了 Cu/ZSM - 5 催化剂, 利用 XRD IR BET 和 SEM 等手段 催化剂样品进行了表征, 考察了不同方法制备的改性 ZSM - 5 催化剂上Cu的负载量. 结果表明, 在相同原料质量比下(M ( Cu (AC) ) BM (HZSM - 2 5) = 1B5), 微波固相法制备的催化剂中, Cu的负载量为 5. 65%; 离子交换法制备的 催化剂中, Cu的负载量为 1. 86% , 且微波固相法所需时间仅为传统加热条件下离子 交换法所需时间的 1/39, 同时微波辐射能促进了活性组分在分子筛表面及孔道上的 分散和固态离子交换反应. NO催化分解反应活性结果表明, 微波固相法制备的催化 剂具有更高的催化分解活性及稳定性. : Cu /ZSM - 5分子筛; 一氧化氮; 催化分解; 微波辐射; 固态相互作用 : O643. 3 : A Preparation ofCu/ZSM- 5 Catalysts by DryReaction under M icrowave Irradiation and TheirCatalyticPerformances 1, 2 1 1 Y NG Peng-fei , ZHOU Ji-cheng, RENWen-m ing ( 1. School of Chemistr and Chem ical Engineering, Un iversit of south china, Heng ang, Hunan 421001, Ch ina; 2. Ke Laborator of Green Catal sis and Chem icalR eaction Engineering ofHunan Province, School ofChem icalEngineering, X iangtan Un iversit, X iangtan, Hunan 4 11105, Ch ina) bstract: Cu/ZSM - 5 molecu lar sieve catal sts w ere prepared b dr reaction under m i- crow ave irradiation and ion- ex change. The catal stsw ere characterized b X - ra diffrac- tion, infrared spectroscop , BET surface area, scanning electron m icroscop . The Cu load- ing in the catal sts