热解过程中玉米秆颗粒孔隙结构的演化-中国电机工程学报.PDF

第28 卷 第35 期 中 国 电 机 工 程 学 报 Vol.28 No.35 Dec. 15, 2008 108 2008 年12 月15 日 Proceedings of the CSEE ©2008 Chin.Soc.for Elec.Eng. 0258-8013 (2008) 35-0108-06 TK 6 A 470 20 文章编号： 中图分类号： 文献标志码： 学科分类号： ⋅ 热解过程中玉米秆颗粒孔隙结构的演化 付鹏，孙路石，胡松，向军，杨涛，陈巧巧，张军营 (煤燃烧国家重点实验室(华中科技大学) ，湖北省 武汉市 430074) Evolution of Pore Structure of Maize Straw Particles During Pyrolysis FU Peng, SUN Lu-shi, HU Song, XIANG Jun, YANG Tao, CHEN Qiao-qiao, ZHANG Jun-ying (State Key Laboratory of Coal Combustion (Huazhong University of Science and Technology), Wuhan 430074, Hubei Province, China) ABSTRACT: The changes in pore structure characteristics of 的形状发生了一定的变化，各种孔的比例有了较大变化，且 maize straw (MS) particles during pyrolysis were studied. The 孔径有先变小后变大的趋势。高温导致焦颗粒发生塑性变 samples were characterized by N2 isothermal adsorption/ 形，使得孔隙扩大和孔表面更加光滑。随着温度的升高， desorption method and scanning electronic microscopy (SEM). 玉米秆焦的BET 比表面积经历一个先减小后增大再减小的 The results indicate that pyrolysis temperature has a notable 过程，500 ℃以前，孔容积的变化规律与比表面积相近， impact on the pore structue and morphology of biomass char. 但当温度高于500 ℃时，比表面积在减小，而孔容积在增 Pyrolysis temperature is found to influence the size and the 大。通过分形FHH方程回归得到的分形维数DFHH 能较好地 shape of char particles. High temperature leads to plastic 表征颗粒内部孔隙表面的分形特征。其分形特征与热解温 deformation of particles resulting in smooth surfaces and large 度密切相关，分形维数DFHH 的变化与BET 比表面积SBET 有 cavities. Brunauer-Emmett Teller (BET) specific surface area 一定关联。 SBET undergoes a complex process during pyrolysis: firstly 关键词：玉米秆；热解；孔隙结构；吸附/脱附；分形维数 decreases to 1.518 m2/g at 250 ℃, increases to a maximum 2