天然气脱硫过程分析及应对措施陈建兵1叶帆2赵德银2薄德臣11.DOC

天然气脱硫过程分析及应对措施 陈建兵1 叶帆2 赵德银2 薄德臣1 （1 中国石油化工股份有限公司大连石油化工研究院 辽宁省大连市 116041 2中国石油化工股份有限公司西北油田分公司 新疆乌鲁木齐市 830054） 摘 要：国内油田在开采过程中会副产部分天然气，这部分天然气需要经过一系列的工艺过程才能得到合格的天然气产品；但天然气在净化过程中存在脱硫塔出现频繁的发泡拦液现象，脱硫塔运行不稳定且天然气脱硫塔效率较低，产品天然气硫含量不达标。采用ASPEN PLUS和冷模实验对天然气脱硫过程进行深入研究。研究发现：（1）操作压力从1.0MPa升高到2.1MPa时，硫化氢含量从55.6mg/m3减少至48.9 mg/m3；吸收温度从31℃升高到55℃时，硫化氢含量从46mg/m3升高至至48.5mg/m3；塔板数从15块增加至23块，硫化氢含量从278mg/m3减少至13mg/m3。（2）在塔盘开孔等条件相同及阀孔动能因子为19m/s(kg/m3)0.5的情况下，FMP塔盘的液泛夹带量为0.07~0.08kg/kg，F1浮阀塔盘为0.16kg/kg。工艺参数对脱硫效果影响较小，造成脱硫塔发泡拦液现象的根本原因在于鼓泡传质过程以及原料中重组分物质在吸收剂中的累积。采用FMP塔盘技术可以解决脱硫塔发泡拦液所造成的运行不稳定和脱硫效率低的问题。 关键词：天然气；脱硫；立式喷射；FMP 中图分类号：TQ028.1 文献标识码：A Analysis and countermeasures of natural gas desulfurization process. Chen Jianbing1 Ye Fan2 Zhao Deyin2 Bo Decheng1 (1 The Dalian Petrochemical Research Institute, Dalian Liaoning 116041 China 2 Northwest oil field branch, Xinjiang Urumqi 830054 China) Abstract: Domestic oil fields will produce some natural gas in the process of mining. This part of natural gas needs a series of technological processes to get qualified natural gas. However, in the process of purification, there are frequent foaming phenomena in desulfurization tower that is unstable and less efficient, which result in the sulfur content of natural gas is not up to standard. The process of natural gas desulfurization was studied by ASPEN PLUS and LengMo experiment. The study showed that: (1) when operating pressure was increased from 1.0MPa to 2.1MPa, the content of hydrogen sulfide decreased from 55.6mg/m3 to 48.9mg/m3; temperature rise from 31℃ to 55℃, the content of hydrogen sulfide from 46mg/m3 rise to 48.5mg/m3; The number of plates increased from 15 to 23, and the content of hydrogen sulfide decreased from 278mg/m3 to 13mg/m3. (2) under the same tray conditions and the same kinetic factor of the valve (19m/s(kg/m3)0.5), the foam entrainment on the FMP tray was 0.07~0.08kg/kg, and the F1 valve tray was 0.16kg/kg. The effect of process parameters on desulfurization effec