催化剂对天然焦–蒸汽气化特性的影响-中国电机工程学报.PDFVIP

第 29 卷 第 8 期 中 国 电 机 工 程 学 报 Vol.29 No.8 Mar.15, 2009 2009 年 3 月 15 日 Proceedings of the CSEE ©2009 Chin.Soc.for Elec.Eng. 45 0258-8013 (2009) 08-0045-05 TQ 517 A 470 20 文章编号： 中图分类号： 文献标志码： 学科分类号： ⋅ 催化剂对天然焦–蒸汽气化特性的影响 1 1 2 向文国，赵长遂，庞克亮 (1．东南大学能源与环境学院，江苏省 南京市 210096 ； 2．国家电站燃烧工程技术研究中心，辽宁省 沈阳市 110034) Influence of Catalysts on Natural Coke-steam Gasification Characteristics 1 1 2 XIANG Wen-guo , ZHAO Chang-sui , PANG Ke-liang (1. School of Energy and Environment, Southeast University, Nanjing 210096, Jiangsu Province, China; 2. National Power Plant Combustion Engineering Research Center, Shenyang 110034, Liaoning Province, China) ABSTRACT: Experiments were carried out to study the 气量提高 1.75 倍，小时产气热值提高近 2 倍。 influences of catalysts on the natural coke-steam gasification 关键词：天然焦；催化剂；蒸汽气化 characteristics in a bench scale fluidized bed. Four catalysts including K, Ca, Fe, Ni catalysts and their mixture were tested. 0 引言 The experimental results show that the gasification reaction 天然焦是煤层受岩浆侵入，快速热解、干馏而 rate, product gas yield, carbon conversion rate and gas heating 成的固体可燃矿物，热值为 18~30 MJ/kg 。由于天 value per hour increase when K, Ca, Fe, Ni catalysts are added