煤与含氟聚合物对聚酯结构与性能的影响研究-材料学专业毕业论文.docxVIP

Effects Effects ofcoal and fluoropolymers the structure and properties ofpolyester Abstragt Effects of coal and fluoropolymers on the structure and properties of polyester Abstract The purpose of this thesis is to investigate the effects of coal，ammonium polyphosphate(APP)and their combination system，fluoropolymers on the structure and properties of poly(ethylene terephthalate)(PET)and phosphorus—containning copolyester (fPET)．The flame·retardant properties of the modified PET and fPET were studied with limited oxygen index method，horizontal and vertical buming methods aS well aS charring experiments．Thermal behavior,thermal degradation characteristics and flame retardant mechanism of the two polyesters were studied witll the cone calorimetry and thermogravimetry．Differential scanning calorimetry(DSC)WaS used to analyse crystallization of the polyesters．In addition，the mechanical properties of the modified PET and fPET were tested with multipurpose test machine．The rheological properties of the modified polyesters were evaluated with the parallel plate rheometer．Finally,the bench scale spinning experiments including spinning and drawing and texturing were carried out for the copolyester in the presence of additives．The mechanical properties， flame—retardancy and dyeing of the copolyester fibers were assessed． Effects of coal and fiuoropolymers on the structure and properties ofpolyester The main important findings are as follows： (1)APP accelerated thermal degradation of PET and of fPET．Co姻P flame retardant system has synergistically improved the charring and flame retardant properties of PET and fPET．The results from Cone calorimetry showed that，the Coal／APP flame retardant system significantly reduced the heat release rate(rmR)and the peak heat release rate(pk-HRR)of PET,and the flame retardation of the Coal／APP system WaS evidenced in the condensed phase．Unfortunately,the mechanical properties of the PETs were deteriorated in the presen