水杨醛缩苯乙酰腙对锌离子的高选择性识别.pdf

9 　　　　　　 　 ·529 · 1, 2 2 , 　 (1. , 364000;2., 361005 ) 　:设计合成了用于识别锌离子的荧光传感分子———水杨醛缩苯乙酰腙(1),通过红外光谱、 磁共振谱和质谱表征其结构;利用其荧光性质研究了该物质对几种过渡金属离子的识别性质,初步 探讨了其结合模式。实验表明:在乙腈介质中,主体分子 1 表现出对Zn2+良好的选择性,Zn2+ 的加 入导致 1 的长波长荧光增强437 倍,而其它过渡金属只引起1 的荧光略微增强, Job 法实验揭示1 与Zn2+ 的结合比为1 ∶1。 :水杨醛缩苯乙酰腙;锌离子;荧光传感;分子识别 :O 657.39　　　:A :0367-6358(2009)09-0529-03 Highly Selective Recognition of Zinc Ion by S licyl ldehyde-2-phenyl cetylhy dr onde W U Lin-hu 1,2 , 　XUE W ng-xin2 (1.Department of Chemical and Materials Eng ineering, Longy an University , Fuj ian Longy an 364 , China; 2 .Department of Chemistry , College of Chemistry and Chemical Engineering, X iamen Universtty , F uj ian X iamen 361 5, China) Abstract:A fluorescent chemosensor, s licyl ldehy de-2-phenyl cetylhydr zone (1 ), w s designed nd 1 synthesized .1 w s confirmed by IR, H NM R nd ESI-MS.1 w s found to recognize tr nsition met l ions such s Zn2+、Cu2+、Hg2+、Pb2+ nd Ni2+ vi its fluorescence spectr .M ech nism of enh ncement of 1s 2+ fluorescence by Zn w s briefly discussed.It w s found th t 1 show ed highly selective response to 2+ 2+ Zn .In cetonitrile Zn induced dr m tic enh ncement in the fluorescence of 1 by 437 folds, w here s the other tr nsition met l ions h d little influence.Jobs test show ed 1 coordin ted w ith Zn2+ to form 1 ∶ 1 model complex . 2+ Key words: s licyl ldehy de-2-phenyl cetylhydr zone;Zn ;fluorescence enh ncement ;molecul r recognition [6-8] 　　 , , 。