铝电解质初晶温度测定及应用研究-分析化学专业毕业论文.docxVIP

中南大学硕士学位论文 中南大学硕士学位论文 ABSTRACT ABSTRACT Crystallization temperature and cryolite ratio are important parameters in Hall—Heroult for aluminum electrolysis．Low crystallization temperature enables low bath temperature．The current efficiency increases with the decreasing of bath temperature．It is difficult to determine the temperature parameters of the aluminum electrolyte because of its corrosive nature and hi曲temperature．It has become an important task to exactly measure crystallization temperature and cryolite ratio quickly． Probe for measuring crystallization temperature of aluminum electrolyte Was studied in present paper．The basic constitution of the probe Was designed，and a suitable thermocouple and sampling implement for this method were obtained through experiments．On the basis of this method and the characteristics of the bath,improvement of the probe for covering shortage WaS studied and made progress． Vmual device systerm for crystallization temperature automatic detection Was set up．Data manage programme and instrument control panel were developed by use of labview programming language．It tumed out systerm can gather and analysis a great deal of temperature datas， display cooling curve clearly,and find out Crystallization temperature well and truly． Relationship of cryolite ratio，additives and Crystallization temperature of the system Na3AIF6-A1203一MgF2一CaF2一LiF was tested,a BP neural network model Was obtained and proved by experiments of actual aluminum electrolyte．The results show the deviation between the predicted value of liquidus temperature gained from the model and the measured is wimiIl±3℃．The deviation between of predicted value of liquidus temperature gained from the model and the measured is within +0．07． KEY WORDS： aluminum electrolyte，crystallization temperature， temperature measuring probe，BP neural network model lI 原创性声明本人声明，所呈交的学位论文是本人在导师指导下进行的研究 原创性声明 本人声明，所呈交的学位