钯催化卤代芳烃Ullmann偶合反应Palladium.pdfVIP

2005 25 Vol. 25, 2005 2 , 147151 Chinese Journal of Organic Chemistry No. 2, 147151 ·· Ullmann * ( 410081) Ullmann . Ullmann , Ullmann Ullmann . ; ; Ullmann ; ; Palladium-Catalyzed Ullmann-Type Coupling of Aryl Halides LIANG, Yun LI, Jin-Heng* (Key Laboratory of Chemical Biology Traditional Chinese Medicine Research, College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081) Abstract Ullmann-type coupling reaction is one of the most important methods to construct CC bonds in organic synthesis. Recent advances in the palladium-catalyzed Ullmann-type coupling of aryl halides in- cluding reductive coupling and oxidative coupling reactions have been reviewed. Keywords palladium; aryl halide; Ullmann reaction; oxidative coupling; reductive coupling Ullmann . Ullmann , , ( 1 Ullmann ) . 1.1 Ullmann Ullmann Ullmann . Ullmann Pd/C, 1901 [13], , . , , ( , )( . , ). , ()Ullmann , [418]. , Ullmann Ullmann , (Scheme 1). (Eq. 1). * E-mail: jhli@mail.hunnu.edu.cn Received January 31, 2004; revised April 29, 2004; accepted June 7, 2004. (No.(No. 02C211). 148 Vol. 25, 2005 ,