第 24 卷第 3 期 中国有色金属学报 2014 年 3 月
Volume 24 Number 3 The Chinese Journal of Nonferrous Metals March2014
文章编号:10040609(2014)03080806
高铁铝土矿与硫酸氢铵混合焙烧工艺
辛海霞,吴 艳,刘少名,翟玉春
(东北大学 材料与冶金学院,沈阳 110004)
摘 要:针对传统处理高铁铝土矿能耗高、金属提取率低等缺点,提出硫酸氢铵焙烧工艺。在分析广西高铁铝土
矿热分解过程的基础上,研究硫酸氢铵加入量、焙烧温度和焙烧时间等工艺参数,采用 XRD 对反应产物物相进
行表征。结果表明:在硫酸氢铵与铝土矿质量比为3.5:1、焙烧温度为 450 ℃、焙烧时间 60 min 的条件下,铝和
铁的提取率分别为 93%和 95%以上;铝反应的产物为 NH Al(SO ) ,铁反应的中间产物为(NH ) Fe(SO ) ,最终产
4 4 2 4 3 4 3
物为 NH Fe(SO ) 。该工艺具有焙烧温度低、金属提取率高等特点,对广西高铁铝土矿的开发利用具有重要意义。
4 4 2
关键词:高铁铝土矿;硫酸氢铵;焙烧工艺
中图分类号:TF821 文献标志码:A
Roasting process of mixture of
high ferric bauxite and ammonium bisulfate
XIN Haixia, WU Yan, LIU Shaoming, ZHAI Yuchun
(School of Materials and Metallurgy, Northeastern University, Shenyang 110004, China)
Abstract: Anovel process of roasting highiron bauxite using ammonium bisulfate wasproposed to overcome the defects
of traditional process, such as high power consumption and low extraction rates. First, the thermodynamics in
decomposition process of highiron gibbsitic bauxite resource in Guangxi was analyzed. Then, various parameters
including ammonium bisulfate addition, roasting temperature and roasting time were investigated. The product was also
characterized by XRD. The results show that extraction rates of over 93% and 95% respectively for aluminum and iron
are obtained after roasting at 450
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