绿色水处理剂聚环氧琥珀酸物化性能指标及表征技术-应用化学专业毕业论文.docxVIP

绿色水处理剂聚环氧琥珀酸物化性能指标及表征技术摘要 绿色水处理剂聚环氧琥珀酸物化性能指标及表征技术 摘要 聚环氧琥珀酸是目前国际上公认的绿色水处理剂及更新换代产品。由于其问 世时间较短，国内外还未建立企业标准、行业标准和国家标准，各项物化性能的 测试方法还无可供参考的数据，这在很大程度上影晌了聚环氧琥珀酸研究的深化 和推广应用。 本文采用红外光谱法、电导滴定法、凝胶渗透色谱、静态阻垢法、OECD301B 标准方法等系统地测定了聚环氧琥珀酸的分子量、活性物含量、可生物降解性能、 阻垢缓蚀性能等一系列物化性能，提出了这些物化性能的测定方法。 测定结果表明，采用凝胶渗透色谱测定聚环氧琥珀酸的分子量可以得到准确 完整的分子量数据和分子量分布：用电导滴定法测定活性物含量可以得到可靠的 结果，同时讨论了样品浓度、滴定剂浓度和滴定速度对滴定结果的影响，确定了 最佳滴定条件；静态阻垢法和电导滴定法适合于测定聚环氧琥珀酸的阻垢性能， 标准旋转挂片法可以用来测定聚环氧琥珀酸的缓蚀性能；OECD301B标准方法 对于测定聚环氧琥珀酸和其它聚羧酸型阻垢剂的可生物降解性能是一种非常合 适的方法，并从分子结构探讨了聚环氧琥珀酸的可生物降解性机理，得出聚环氧 琥珀酸具有优良可生物降解性主要原因可能由于其分子链中插入了氧原子。 关键词：聚环氧琥珀酸绿色化学生物降解阻垢缓蚀分子量 北京化T人学坝11毕业论史Characterization 北京化T人学坝11毕业论史 Characterization of Physical and Chemical Properties of Polyepoxysuecinic acid ABS’I’RAC’I’ Potyepoxysuecinic acid(PESA)which is free of nitrogen and phosphorus is of the three green water treatment agents recognized through the world． Being studied in many aspects because of its excellent performances although，the characteristic techniques for physical and chemical properties of PESA have been standardized．This has influenced PESA’S study and application to large extent． In this paper,the molcular weight of PESA，the of carboxyl group in PESA，scale—inhibition and corrosion—inhibition，the biodegradability,etc．were determined by many methods such as the IR spectroscopy,conductometry,Gel Permeation Chromatography(GPC)，OECD301B standard method and The determination results indicate that the accurate and intact molecuar weight data of PESA and the distribution Can be achieved by GPC，the of carboxyl group in PESA be determined by conductometric titration，And the suitable condition of the titiration was presented simultaneously．The effective factors，such concentration of the sample and the titrant，rate of titration were discussed in this Papel． OECD301B standard method is an ideal method determine the biodegradability of PESA other polycarboxylates scale—inhibitors The biodegredation mechanism of PESA is also discussed from molecular structure in