铝镍钴合金的磁稳定性研究-材料物理与化学专业毕业论文.docx

万方数据 万方数据 Classified Index: TB31 U.D.C: 621.785 Thesis for the Master Degree in Engineering STUDY OF MAGNETIC STABILITY OF ALNICO ALLOY Candidate： Liao Yaqin Supervisor： Prof. Jiang Longtao Academic Degree Applied for： Master of Engineering Speciality： Materials Physics and Chemistry Affiliation： Materials Science and Engineering Date of Defence： July, 2014 Degree-Conferring-Institution： Harbin Institute of Technology 哈尔滨工业大学工学硕士学位论文 哈尔滨工业大学工学硕士学位论文 摘 要 铝镍钴合金因其良好的温度稳定性得到广泛应用，由于测试设备的限制，无 法精确表征铝镍钴合金随时间磁性能的稳定性。在此背景下，本文通过搭建硬磁 材料无损伤磁电性能测试装置；通过小梯度温度升温实验，优选出-70℃~130℃、 -70℃~190℃、-196℃~130℃和-196℃~190℃四种冷热循环稳定化工艺；通过 XRD、 EBSD、TEM 和 MFM 研究了不同批次的铝镍钴微观组织相结构、晶粒尺寸及取向、 织构和微观组织的变化。 铝镍钴合金具有体心立方结构，晶体取向是100方向，空间构型是柱状晶； 随温度升高，铝镍钴合金的表观磁畴逐渐变大，且有序性和均匀性降低；随时间 延长，铝镍钴合金的表观磁畴逐渐变大，且有序性和均匀性降低。 经冷热循环稳定化处理的铝镍钴合金，其表观磁畴随冷热循环温差增加而增 大，磁感应强度冷热循环温差增加而增强；经冷热循环后，铝镍钴合金 α1 和 α2 相 有序性增加，晶粒尺寸无明显变化。铝镍钴合金长期稳定性测试中，随冷热循环 温差增大，磁不可逆损失减小；磁钢贮存时间越长，其磁不可逆损失越小。 经时效稳定化处理的铝镍钴合金，元素相互扩散，α1 和 α2 相有序性增加，晶 粒长大且均匀性增加，表观磁畴变大；经时效冷热循环稳定化处理的铝镍钴合金， Alnico8-1 型合金在长期稳定性测试中稳定性优于其他批次。 关键词：铝镍钴合金；冷热循环；长期稳定性；微观组织 -I- Abstract Alnico has been widely used as its good temperature stability. Due to the limitation of the facility. The magnetic stability over time of alnico can not be characterized accurately. In this paper, a no damage magnetic and electric properties testing device for hard magnetic materials was created. Four thermal-cold cycle (TCC) stabilization process:-70℃~130℃、-70℃~190℃、-196℃~130℃ and-196℃~190℃ were chosen through a small temperature step stress test。XRD、EBSD、TEM and MFM were used to research the microstructure of phase、changing of texture、grain size and orientation . Alnico is body-center cubic structure.Its crystal orientation is 100 and Space configuration is columnar crystal..As the rise of the temperature and longer of the aging time, The magnetic domain increases gradually, but the order and uniformity of the alloy are lower. After the TCC process, The magnetic domain became bigger with increasing temperat