镀液中稀土掺杂对镍基化学镀的影响-表面技术.PDF

摇摇摇 44 张敬尧等摇 镀液中稀土掺杂对镍基化学镀的影响 镀液中稀土掺杂对镍基化学镀的影响 1,2 1 张敬尧 ,杨秋菊 (1.扬州大学 机械工程学院,扬州225127;2.南京理工大学 材料科学与工程学院,南京210094) 3+ 3+ 3+ 摇 摇 [摘摇 要]摇 在酸性镍基化学镀液中掺杂稀土离子Y ,Nd 或La ,研究了稀土对镀液稳定性、沉积速度及镀 层性质(组织结构、显微硬度和耐蚀性能)的影响。 结果表明:添加微量稀土即能提高镀液稳定性和沉积速度,其 3+ 3+ 中Y 的效果最明显,而La 的效果最差;稀土应用于化学镀中可有效细化镀层晶粒,提高镀层硬度和耐蚀性。 [关键词]摇 稀土掺杂;镀液稳定性;沉积速度;组织结构;显微硬度;耐蚀性 [中图分类号]TQ153.1 摇 摇 摇 [文献标识码]A 摇 摇 摇 [文章编号]1001鄄3660(2012)06鄄0044鄄03 Effects of RE鄄doped in the Bath on Nickel鄄base Electroless Deposit 1,2 1 ZHANGJing鄄yao ,YANG Qiu鄄ju (1.Institute of Mechanical Engineering,Yangzhou University,Yangzhou225127,China;2.Institute of Material Science and Engineering,Nanjing University of Science and Technology,Nanjing210094,China) 3+ 3+ 3+ [Abstract]摇 The rare earth ions of Y ,Nd or La was doped in acidic Ni鄄base electroless bath respectively,then the effects of RE onthebath stability anddeposit rateandcoatingorganize structure,aswell asmicrohardnessandcorrosionresist鄄 ance of coatingswerestudied. Theresultsshowthat REelementwithalittleamountdopedintheelectrolessbathcouldincrease 3+ 3+ the bath stability and deposit rate,where the effect of Y isremarkablewhilethat of La isworst. At the sametime,RE used in electroless deposit could make nickel grain smaller and raise microhardness and corrosion resistance of coating availably. [Key words]摇 RE鄄doped;bath stability;deposit rate;organize structure;microhardness;corrosion resistance 摇 摇 随着镍基化学镀合金在工业、民用、国防等领域越 次亚磷酸钠30 g/ L,乙酸钠20 g/ L,苹果酸10 g/ L,稀 来