镁合金钛盐转化膜分析-材料物理与化学专业毕业论文.docxVIP

西安建筑科技大 西安建筑科技大 学硕士学位论文 西安建筑科技 西安建筑科技大学硕士学位论文 Titanium-based Conversion Coating on AZ31B MagnesiumAlloy Specialty: Environmenta l Engineering Name: Lan Liqiang Instructor: Prof Guo RlIiguang ABSTRACT Because of the excellent characterist ics of Iight weight ，high specific st iffness， casting prope民y ，mechanical process property，good damping property and so on， magnesium and its alloys are applied widely in aerospace，automobile ，electronics， mechanical industry. However，magnesium alloys exposed in practical application environment are susceptible to corrode due to highly reactive property and their further applications are lirnited. In order to enable magnesium alloys to obtain better application，people developed many anticorrosion methods. One of them is chromate chemical conversion coating technology . Chromate chemical conversion coating technology is applied widely because of convenient operation，low cost and excellent performance. However，the hexavalent chromium ions is great harmful to the peoples health and the environment. China began to caηy out the EU RoHS (reduction of hazardous substances) directive in 2007，which prohibited to use six hazardous substances including hexavalent chromium，lead and SO on in the production process. Therefore，the development of clu-omium-free conversion processing technology ha s become very urgent. At present ，the research of chromium -free conversion coating on magnesillm alloys focused on the phosphate，Stannate ，rare eart h，organic process and so on. To some e-..1e时，these methods played a protective role in the metal surface. However， these technologies had more or less shortcomings such as poor corrosion resistance， waste water treatment difficulties，high energy consumption，environmental pollution and so on. Firstly，the titanium chemical properties are very similar to chromium and titanium can form different oxidation states. Secondly，titanium can form an inert ， stable and exceUent corrosion resistance of de