温州市灰霾污染的特征与成因分析.docVIP

温州市灰霾污染的特征与成因分析 徐港 王斯 李鹏飞 俞绍才 刘维屏 郑仙珏 教育部重点实验室空气污染与健康研究中心杭州市 环境监测中心站 摘要: 利用高时空分辨率的监测数据，结合混合受体模式，运用统计学分析方法，研 究温州市2013—2014年大气污染物时间变化特征，并对2013年12月初严重灰 霾污染事件进行案例分析。结果表明:春、冬季PM2. 5平均值明显高于夏、秋季。 本地PM2. 5浓度受二次细颗粒物的形成、区域传输以及气象条件的影响，交通运 输源是重要来源。春季PM2. 5/C0 （质量比）最高（尤其在凌晨和下午两个时段）， 此时二次细颗粒物的贡献较大。案例分析发现，安徽省及长三角地区的工业化发 达区域（特别是上海市、宁波市等沿海城市）是温州市严重灰霾污染的主要潜在 源区;沈阳市也是重要潜在源区，传输路径为海上通道。 关键词: 灰霾;统计学分析方法;混合受体模式;污染特征;成因; 作者简介：徐港，男，1994年生，本科，研究方向为大气污染。 收稿日期:2016-07-19 基金：国家自然科学基金资助项目（No.No. 41561144004） Characteristics and origins of haze pollution in Wenzhou XU Gang WANG Si LI Pengfei YU Shaocai LIU Weiping ZHENG Xianjue Key Laboratory ofEnvironmentRemedi a Ecological Hea1th, Ministry of Education, Research Center for Air Pollution and Hea1th, College of Environmental Resource Sciences, Zhejiang University; Hangzhou Environmentai Monitoring Center; Abstract： To identify sources and characteristies of haze pollution in Wenzhou, statistical analysis met hod was used to study the temporal varia tions of air pollution from March 1 st, 2013 to February 28 th, 2014.The observational data with the high spatial-temporal resolution and hybrid receptor models were used in this study. In addition, a case study for a heavy heize epi sode from November 25 th to December 11 th, 2013 was carried out. The results revealed that PM2. 5 showed signifiedntly higher concentrations during the spring and winter than the summer and autumn. PM2. 5 levels were affected by other factors such as meteorological conditions, secondary fine particulate production, regional transport processes. Vehicle emissions were one of the major sources. The PM2. 5/C0 （mass fraction） was the largest in spring, especially in the early morning and afternoon, reflecting a significant contribution of secondary fine particulate formation. The case study indicated that PM2?5 pollution in Wenzhou mainly originated from the industrial zones in the Anhui Province and Yangtze River Delta, especially from the coastal cities such as S