枝孢霉菌对A3钢腐蚀的影响-材料工程.PDF

A3 55 A3 Influence of Cladosp or ium on Corrosion Behavior of Steel A3 ,, , (, 100083) LI Song-mei, WA G Yan-qing, LIU Jian-hua, LIA G Xin (School of Materials Science and Engineering, Beijing University of Aeronautics and Astronautics,Beijing 100083, China) : A3 , A3 0 7 ,2 7 A3 , , 15 25mV 2,7 , A3 15 , 15,A3 , , A3 , A3 : ; ; : TG1727 : A : 1001-4381(2008) 07-0055-04 Abstract : The influence of cladosporium on the corrosion behaviors of Steel A3 was studied using open circuit potential(Eocp) , Electrochemical Impedance Spectroscopy(EIS) and Scanning Electron Micros- copy ( SEM) . T he results of electrochemical test indicated that the electrochemical behaviors of steel A3 were influenced by the present of cl adosp or ium . Eocp of the systems with and without bacteria all shifted positively at first, and then negatively during the7 days of immersion. After 2 days and 7 days of immersion, Eocp in the system with cl adosp or ium was more negative than that in the sterile med-i um on the same day, which showing a higher electrochemicalactivity on themetal surface. On the 15th day of immersion, Eocp in the system without bacteria going to steady while Eocp in the system with bacteria shifted to positive about 25mV. T he results of EIS were consistent with the results of Eocp nd th on the 2 and 7 day. Samples in the system with c ladosp ori um reached a lower resistance value than in the sterile medium on the 15th day. SEM results showed that crazing occurred on steel A3 in the sterile medium while serious pitting corrosion occurred on them