力致超长室温磷光材料及其光致三色发光转换-国家级大学生创新创业.PDFVIP

力致超长室温磷光材料及其光致三色发光转换 华南师范大学 黎建桉，周京弘 （1．华南师范大学化学与环境学院，广东省广州市510006； 2 ．华南师范大学化学与环境学院，广东省广州市510006 ）1 Jian-An Li （黎建桉）, Jinghong Zhou （周京弘）, Zhu Mao, Zongliang Xie, Zhan Yang, Bingjia Xu （许炳佳， 通讯作者）, Cong Liu, Xin Chen, Dingyang Ren, Hui Pan, Guang Shi （石光，通讯作者）, Yi Zhang, and Zhenguo Chi. Transient and Persistent Room-Temperature Mechanoluminescence from a White-Light-Emitting AIEgen with Tricolor Emission Switching Triggered by Light (Angewandt Chemie Internation Edition 2018, 57, 6449 –6453) 指导老师：许炳佳 副研究员 中文摘要：纯有机材料的超长室温磷光基本上是由光或电触发产生的，这在很大程度上限制了它们的实际应用。该研究 通过在N- （4-三氟甲基苯基）邻苯二甲酰亚胺中引入重卤原子溴的方法开发出了第一例能够在室温下同时表现出光致超长磷 光发射、力致瞬时荧光发射和力致超长磷光发射特性的纯有机聚集诱导白光化合物。在开-关紫外灯的过程中，化合物的晶 体粉末还能实现蓝光、白光和黄光之间的三色发光转换。单晶结构分析和量子化学计算结果表明，化合物力致超长室温磷光 发射产生的机理与分子中溴原子较强的自旋轨道耦合作用、非中心对称晶体结构中 H-聚集体的形成及分子内运动受限等因 素有关。 英文摘要：Persistent luminescence from purely organic materials is basically triggered by light and electricity, which largely confines its practical applications. A purely organic AIEgen exhibits not only persistent photoluminescence, but also transient and persistent room-temperature mechanoluminescence. By simply turning on and off a UV lamp, tricolor emission switching between blue, white, and yellow was achieved. The data from single crystal structure analysis and theoretical calculation sug gest that mechanism of the observed persistent mechanoluminescence (pML) is correlated with the strong spin–orbit coupling of the bromine atom, as well as the formation of H-aggregates and restriction of intramolecular motions in noncentrosymmetric crystal structure. These results outline a fundamental principle for the development of new pML materials, providing an important step forward in expanding the application scope of persistent luminescence. 关键词：聚集诱导发光；超长室温磷光；三色发光转换；白光发射