空化水射流结合H2O2氧化处理苯酚废水实验研究-安全技术及工程专业毕业论文.docxVIP

PAGE PAGE IV ABSTRACT Phenolic contamination is a sort of representative organic pollutants which are difficult to be degraded. The numerous amount of phenolic contamination is doing great harm to the environment and can be widely found in industrial waste water. So it must be discharged with an adequate treatment. The disposal methods of phenolic waste water include physical chemistry technology, biology and advanced oxidation technology, etc. However, these methods all have some shortcomings, for instance, treatment is not thorough. High presssure and high temperature could be produced after the crumble of cavitation bubble, which could impel the H2O2 in the solution to decompose into ·OH and degradation of organic contamination. Some scholars have applied it to the purification of some wastewater such as PCP, benzene and toluene, but further research needs to be carried out on phenolic waste water with cavitation technology. This paper adopts three ways to deal with phenolic waste water and explores each kind of effecting effect on removal of phenol, these three ways are the technology of H2O2 oxidative degradation, the technology of cavitating water jets and the technology of H2O2 oxidative degradation combined with cavitating water jets. The intermediates and by-products of the technology of H2O2 oxidative degradation combined with cavitating water jets on phenol were analyzed with HPLC and the mechanism of reaction also has been confirmed. Meanwhile the dynamical model of the technology of H2O2 oxidative degradation combined with cavitating water jets has been deduced. The main contents are as follows: ① Through the laboratorial study on the technology of H2O2 oxidative degradation of phenolic water, the optimal reaction condition was concluded: investigated pH 3.0, reaction time 180min, initial phenol concentration 50 mg / L , phenol volume 1L, initial concentration of H2O2 300 mg / L , under this optimal reaction condition, most 31.7% of phenol can be rem