毕业论文：《硫脲改性二乙烯三胺低温固化剂的合成》.doc

中北大学分校毕业设计 PAGE I 硫脲改性二乙烯三胺低温固化剂的合成 摘要：环氧树脂由于具有许多优异的性能，应用十分广泛。然而未经固化的环氧树脂几乎没有多大实用性，需要加入固化剂。固化剂的种类很多，目前低温固化剂普遍使用多胺类固化剂，但多胺类固化剂存在许多不足如具有一定的毒性、在低温下很难固化环氧树脂等，需要对其进行改性来克服这些不足。 本课题使用硫脲对二乙烯三胺进行改性合成低温固化剂，并对制得的固化剂进行红外结构表征。采用单因素分析法考察单体投料比、合成时间及合成温度这些因素对固化剂固化时间的影响，将在不同的实验条件下合成的固化剂与环氧树脂复配得到固化体系，通过测定固化体系的指硬时间和初固时间确定合成固化剂的最佳工艺条件。实验结果表明最佳工艺条件是：单体投料比为1.5：1，合成时间为3h,合成温度为140℃ 。 关键词： 单因素分析法 环氧树脂 固化剂 工艺条件  Thiourea Modify Diethylenetriamine To Make Low-temperature Curing Agent Abstract Epoxy resin with much exceptional performance has application of a very wide range. However without curing the epoxy resin is almost not practical and you will need to add the curing agent.There are many kinds of curing agent.At present the low-temperature curing agent generally use amine, but a number of amine has many deficiencies for example its toxic and it very difficult to solidify the epoxy resin under the low temperature and needs to be modified to overcome these deficiencies. This topic use thiourea to modify Diethylenetriamine to make low-temperature curing agent and characterize the curing agent by IR..We take the single factor analysis to study the influence of the ratio of the added monomers the synthetic time and the curing temperature on the curing time of curing agents,mix the curing agents synthesized in different experimental conditions and epoxy resin to make curing systems, measure the harderned time and preliminary curing time of the curing systems to determine the optimum technological conditions of synthetize of curing agent. The resulting optimum technological conditions are: the ratio of the added monomers of 1.5: 1, synthetic time for 3h, curing temperature of 140 degrees centigrade. Key Words: single factor analysis, epoxy resin,curing agent, technological conditions  目 录 摘 要Ⅰ AbstractⅡ 1 绪论1 1.1 环氧树脂概述1 1.2 环氧树脂的固化反应1 1.2.1 环氧树脂的固化反应类型2 1.3 环氧树脂固化剂7 1.3.1 固化剂的分类7 1.3.2 胺类固化剂9 1.3.3 胺类固化剂改性方法12 1.4 固化反应促进剂概述15 1.5 胺类固化剂对固化物性能的影响16 1.5.1 固化剂