锂离子电池负极材料钛酸锂的制备及性能研究-材料物理与化学专业毕业论文.docxVIP

(4)以预制体Ti02和LiOH为原料，采用微波水热法制备出了Li4Ti5012 (4)以预制体Ti02和LiOH为原料，采用微波水热法制备出了Li4Ti5012 介孔纳米颗粒。低温、短时间反应所生成的产物经煅烧后没有完全发生晶型 转变；过高温和长时间反应使得产物结构变得疏松。本实验条件下，在180℃ 反应120 min的产物煅烧后可以制备出颗粒尺寸约为60 nnl，孔径约为8 nm 的Li4Ti5012介孔纳米颗粒，其在1 C和60 C时的放电比容量分别为173．7 mAh g‘1和90．2 mAh g～。 (5)制备工艺方面，本实验所制备的预制体Ti02的多孔结构和纳米级 短棒有利于溶液中的离子与之发生反应，从而成功得降低了制备“4Ti5012 的煅烧温度和时间。此外，采用微波水热法制各Li4Ti5012在适当提高反应 温度的条件下能够显著地缩短制备周期，提高生产效率。 关键词：锂离子电池，Li4Tis012，共沉淀法，水热法，微波水热法 II 万方数据 Synthesis Synthesis and Properties of Lithium Titanate as Anode Material for Lithium Ion Batteries ABSTRACT As a new anode material for lithium ion battery,spinel—structured lithium titanate(Li4TisO 12)has attracted much interest because of its excellent cycling stability and safety．However,its low electronic conductivity and Li+diffusion coefficient limit its practical applications．Therefore，how to effectively improve its electrochemical performance has attracted increasing attention． In this work，Li4Ti50 12 nanoclusters，open hollow mesoporous microspheres， mesoporous nanoparticles and Li4TisOl2@PANI core—shell nanoparticles were synthesized via the copreciplitation method，hydrothermal method，microwave hydrothermal method and in situ synthesis．The influences of preparation conditions on the physical and electrochemical properties of the products were studied and the results are as follows： (1)Li4Ti50 12 nanoclusters were prepared by a coprecipitation method with C16H3604Ti and LiOH as the starting materials．Large sized Li4Tis012 particles with poor electrochemical performance was obtained at the high calcination temperature during long times．In this study，the Li4TisOl2 nanoclusters witll the diameter of around 1 00-250 am were prepared by calcined at 700℃for 1 h and they exhibited discharge capacities of 1 1 5．9 mAh g—and 70．9 mAh g-1 at O．1 C and 1 0 C，respectively． (2)Li4Ti5012@PANI core-shell nanoparticles were synthesized by an in situ synthesis with Li4Ti5012 and C6HTN as the raw materials．The PANI contents of the products were in