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太原工业学院毕业论文
采用乳液法制备的NBR/MoS2纳米复合材料
减磨抗摩性能的研究
摘要:本论文采用二硫化钼(MoS2)作为橡胶纳米复合材料的减磨抗摩添加剂,采用乳液法制备NBR/MoS2纳米复合材料。旨在解决材料的力学性能、耐磨性能与摩擦因数之间的矛盾。考察MoS2的存在状态与橡胶复合材料的摩擦因数及耐磨性能间的关系,研究MoS2在橡胶基体中的减摩和抗磨机理,为设计和获得具有低摩擦因数和高耐磨性能的橡胶复合材料提供理论指导和实验依据。
采用马来酸酐(MA)、十六烷基三甲基溴化铵(CTAB)、聚乙二醇(PEG)及CTAB与PEG复配体系对MoS2进行有机改性,弱化其片层作用力,经改性后的MoS2与丁腈胶乳使用共混共絮凝工艺(乳液法)制备的复合材料中,MoS2和橡胶基体的相界面结合有所改善,同时MoS2还保持着其特有的片层结构,这有利于保持其减摩的特性。
关键词:乳液法,二硫化钼,复配改性体系,力学性能,摩擦系数
The friction-reducing and anti-wear resistance performance research of NBR / MoS2 composites prepared by latex system
Abstract:In this paper, taking into account the molybdenum disulfide rubber composites as friction-reducing and anti-wear additives, pepared NBR/MoS2 composites by latex system. Designed to address the mechanical properties, wear resistance and the contradiction between the friction factor. Investigated the presence of molybdenum disulfide status and the friction coefficient of rubber and wear resistance of the relationship between the study of molybdenum disulfide in the rubber matrix in friction and wear mechanism for the design and access to a low friction coefficient and high wear.
Using Maleic Anhydride(MA)、Cetyltrimethyl Ammonium Bromide(CTAB)、Polyethylene glycol (PEG) and CTAB and PEG blends with system on the organic modification of molybdenum disulfide,weakening the force between the layers, by the modified molybdenum disulfide and the use of blends of nitrile rubber latex flocculation process (emulsion method) to prepare the composite materials, molybdenum disulfide particles much finer dispersion and more uniform particle size to some of the nano-scale. Molybdenum disulfide and the rubber matrix with improved bonding, while molybdenum disulfide has also maintained its unique lamellar structure, which is conducive to maintaining its friction-reducing properties.
Keywords: latex system, molybdenum disulfide, blends with modified system, mechanical properties, friction coefficient
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