润滑油基础油糠醛精制工艺加助剂脱氮小试研究.docxVIP

第2 4卷 第2 4卷 第1期 石油化工高等学校学报 V01．24 No．1 2011年2月 JOURNAL OF PETR()CHEMICAI。 UNIVERSITIES Feb．2011 文章编号：1006—396X(2011)01—0041—03 润滑油基础油糠醛精制工艺加助剂脱氮小试研究 李东胜1’2， 张 毅2， 宋 毅1， 翟玉春1 (I．东北大学材料与冶金学院，辽宁沈阳110004；2．辽宁石油化工大学石油化工学院，辽宁抚顺113001) 摘要：为了提高润滑油的氧化安定性，用络合萃取的方法对某厂减三线脱蜡油进行了脱氖精制处理的小试 实验。结果表明，糠醛与金属盐的混合溶剂能够有效地脱除脱蜡油中的碱性氮化物，减三线脱腊油的碱氮量由 432．32 pg／g降至91．99肛g／g，其脱氮率为78．12％。减三线脱蜡油糠醛精制工艺实验室的适宜操作条件为：加入 助荆6 g／kg、精制温度118℃、精制时间20 min、剂油体积比2．0、沉降时间30 min。白土精制过程最佳操作条件为： 白土加入质量分教为2．5％，精制温度150℃，精制时间20 min，白土不焙烧。 关键词：润滑油基础油；络合萃取；糠醛精制； 加助剂； 脱氮 中图分类号：TE624 文献标识码：A doi：10．3696／j．issn．1006—396X．2011．01．010 Denitrogeneration of Furfural Refining Process of Lube Base Oil Into Which the Assistants iS Added LI DONG--shen91”，ZHANG Yi2，SONG Yil，ZHAI Yu—chunl (1．Materials and Metallurgy College。Northeastern University，Shenyang Liaoning 1 10004，P．R．China； 2．School of Petrochemical Engineering，Liaoning Shihua University，Fushun Liaoning 113001，P．R．China) Received 14 April 2010；revised 10 November 2010；accepted 2 December 2010 Abstract： In order improve the oxidation stability of lube oil，the denitrogeneration refining laboratory scale and pilotscale experiment had been done systematically for the second and third vacuum side dewaxed oil of No．1 refinery with the method of complex extraction．The results show that the mixed solvent of furfural and metallic salt remove the basic nitrogen compounds in dewaxed oil effectively，the basic nitrogen compounds constituents in dewaxed oil were decreased from 432．32 pg／g 91．99 pg／g，the denitrification was 78．12％．A fitting operation condition that the No．1 refinerys third vacuum side dewaxed oil was well extracted with furfural in laboratory was quantity of additive 6 g／kg，refining temperature 118 ℃，refining time 20 min，solvent oil volume ratio 2．0，settling time 30 min。While fitting operation condition that the refining oil was well extracted with atlapulgite quantity of a