三元共聚有机硅柔软剂及其复配物在棉织物上的应用-纺织化学与染整工程专业论文.docxVIP

三元共聚有机硅柔软剂及其复配物在棉织物上的应用 三元共聚有机硅柔软剂及其复配物在棉织物上的应用 万方数据 万方数据 （相对三元共聚硅油质量百分数）HLB 值为 10 的乳化剂 Lutensol XP50 后，乳液呈透明淡黄色，粒径降低至 26.2nm。用于棉织物柔软 整理能提高整理品的亲水性，但弯曲长度增加，略显刚硬。 比较三元共聚有机硅乳液与常见的几类商品柔软剂在棉织物上 的应用性能。三元共聚有机硅乳液整理织物的柔软、滑爽手感优于聚 乙烯类和脂肪酸衍生物类柔软剂。与氨基有机硅整理剂 WR301CN 加工 的织物相比，三元共聚有机硅乳液的整理品的亲水性、白度较好，柔 软和平滑性较差。 为了提高三元共聚有机硅乳液整理品手感的柔软滑爽性，试验中 选用氨基有机硅柔软剂与之复配。先研究了氨基有机硅柔软剂的氨值 和粘度对手感的影响。结果是，氨值愈大，整理织物的柔软平滑性愈 好，织物的白度则愈差。氨基相近时，粘度较大的氨基硅油 Rodorsil 21650 整理品的亲水性、滑爽性和白度均较佳，故选用 Rodorsil 21650 与三元共聚硅油复配，经复配物整理后的织物获得柔软滑爽的手感。 以三元共聚硅油为主体，加入不同量的 Rodorsil 21650 分别进 行复配，Rodorsil 21650 会使复配乳液的粒径降低。除 Rodorsil 21650 用量为 50%的在－10℃环境中放置 24h 不稳定外，其他复配比 例的乳液稳定性较好。当 Rodorsil 21650 的加入量为 10%时，整理 织物的润湿时间降低了 60%，织物的白度和滑爽性均有改善。 三元共聚有机硅乳液对棉织物柔软蓬松手感的试验。较未处理织 物，三元共聚有机硅乳液对棉织物有一定的柔软效果，但蓬松性变差。 用三元共聚有机硅柔软剂使棉织物获得既柔软又蓬松手感还有待进 II 一步提高。 关键词：三元共聚有机硅，自乳化，复配，手感，亲水性 III APPLICATION OF TERNARY COPOLYMER BLOCK SILICONE OIL AND ITS CPMBINATIONS IN COTTON FABRICS ABSTRACT Excepting of its color, design and other aesthetic, the feeling of soft and comfort of textiles is one important factor to attract consumers, and which is usually achieved through soft finishing. Textiles after soft finishing also become smooth and fluffy according different purpose beside the soft and comfort handle. The usage of organic silicon as a kind of softening agent in soft finishing for textiles has a long history, and the most widely-used kind is modified polysiloxane . in 1997, the first commercial ternary copolymer block silicone softener appeared and nowadays this kind of softener is still attracts increasing attention. because of its property of self emulsifying. Based on one kind of commercial ternary copolymer block silicone (provided by the enterprise), we develop one softening finishing compound for cotton fabrics to get the soft and smooth or soft and fluffy handle. The choice of objective evaluation of the soft finishing effects is very important in this research and in the earlier experiment we choose the Phabr Ometer (Feng BaoYi) instrument and