不同蒸馏压力下的生物油分子蒸馏分离特性研究.PDFVIP

第41卷 第2期 燃摇 料摇 化摇 学摇 学摇 报 Vol.41No.13 2013年2月 Journal of Fuel Chemistry and Technology Feb. 2013 文章编号:0253鄄2409(2013)02鄄0177鄄06 不同蒸馏压力下的生物油分子蒸馏分离特性研究 王誉蓉,王树荣,王相宇,郭祚刚 (浙江大学 能源清洁利用国家重点实验室,浙江 杭州摇 310027) 摘摇 要:采用分子蒸馏分离技术对热敏性生物油在不同蒸馏压力下的分离特性进行了研究。 经过分子蒸馏分离后,生物油被 分离为蒸出馏分油与残留馏分油,蒸出馏分油的得率随着压力的下降而显著增大,在700 Pa 时达到了56.50%(质量分数)。 在馏分油的物理性质方面,蒸出馏分油富集了生物油内的大部分水分,残留馏分油内水分得到了较好的脱除,其中,700Pa下 残留馏分油的水分含量降至4.20%(质量分数)。 结合生物油及馏分油的GC鄄MS分析结果,对乙酸、苯酚、糠醛以及左旋葡聚 糖等生物油内典型化合物在不同蒸馏压力下的分布特性进行了研究,获得了相应化合物在分子蒸馏过程中的富集规律。 结 合分离因子评估模型对生物油内14种代表化合物的富集特性进行了量化评价。 关键词:生物油;分子蒸馏;分离特性;蒸馏压力 中图分类号:TK6摇 摇 文献标识码:A Molecular distillation separation characteristic of bio鄄oil under different pressures WANG Yu鄄rong,WANG Shu鄄rong,WANG Xiang鄄yu,GUO Zuo鄄gang (State Key Laboratory of Clean Energy Utilization,Zhejiang University,Hangzhou摇 310027,China) Abstract:The separationpropertiesof sensitivebio鄄oilusingmolecular distillation technology wereinvestigated under different distillationpressures. Crudebio-oilisdividedintodistillatefractionandresidualfractionafterthe molecular distillation process. The yield of distillate fraction increases obviously with the decline of pressure, which achievesthe highest value of 56.50% under 700 Pa. Most of water is enriched in the distillate fraction while water in residual fractions is effectively removed;water content in the residual fraction under 700 Pa is reduced to 4. 20%. The distribution of some typical compounds, including acetic acid, phenol, furfural, levoglucosan,etc,under different distillation pressures was studied and the separation characteristic of these typical compounds was obtained; based on that, a separation factor model was proposed and a quantitative evaluation wasmade on the enrichment behaviors of 14 compoundsin bio鄄oil. Key words:bio鄄oil;molecular dis