流延成型和模压成型法制备纳米氧化硅压电陶瓷的研究-材料科学与工程专业论文.docxVIP

西安理工大学硕士学位论文 西安理工大学硕士学位论文 Ab Abstract PAGE IV PAGE IV 万方数据 III万方数据 III 万方数据 Title: STUDY OF PIEZOELECTRIC SILICA NANOCERAMICS PREPARED BY TAPE-CASTING AND COMPRESSION FORMING Signature: Signature:Major: Material Science and Engin Signature: Signature: Supervisor: Prof.CHEN Wenge Abstract Compared with other piezoelectric materials, the quartz piezoelectric material has many advantages such as low propagation loss, good consistency, better reproducibility and stability. In order to overcome the high price in the manufacture of quartz piezoelectric material, the silica nanoparticle was chosen as the raw material, then the silica nanoceramic was prepared by tape-casting process and compression forming process, meanwhile the piezocera mics were studied by thermogravimetric analysis(TGA), scanning electron microscope(SEM), X-RAY diffraction(XRD), electrical performance tester and vickers microhardness. The phase transformation in the process of silica ceramics production was also studied. When the silica nanoceramic was prepared by tape-casting method, firstly the colloid and raw nanoparticle were mixed together, the two parts has an assigned weight ratio-1:1, then the tape-casting slurry was casted into green body whose thickness was about 3mm, on the other hand 850oC, 950oC, 1050oC and 1200oC were chosen as the sintering temperature, after sintering, the silica naoceramics which is uniform and crack free had been prepared. The piezoelectric constant d33, dielectric constant and mechanical quality factor became higher with the sintering temperature increased, whereas the dielectric loss was lower in high sintering temperature, the capacity, dielectric constant, dielectric loss and mechanical quality factor decreased with the frequency increased. When the sintering temperature was 1200oC, The maximum piezoelectric constant d33 reached 2.5pC/N, the dielectric constant was 82, the dielectric loss was 7.503 and the mechanical quality factor was 67. When the silica nano