裂解化学蒸气发生-无色散原子荧光法直接测定土壤样品中的砷-水生生物学专业论文.docxVIP

AbstractArsenic Abstract Arsenic which has strong toxicity is widely distributed in nature．The prevention and control of arsenic has been 311 important subject in the field．To develop the content’S detection of arsenic in the sample quickly,accurately and efficiently is one of the important tasks of elemental analytical chemistry． This new study sets up the theory,method，and the equipment of fast pyrolysis-chemical vapor generation for the first time．To combine with nondispersive atomiC fluorescence spectrometry,the method succeeded in direct determination of arsenic in soil samples．The study shows that sodium formate carl react with trace arsenic to form volatile species via fast pyrolysis——chemical vapor generation．We found that the presence of thiourea greatly enhanced the generation efficiency and eliminated the interference of copper Study investigated the factors influencing fast pyrolysis—chemical vapor generation．Working conditions of instrument，such as photomultiplier tube negative voltage，hollow cathode lamp current，and the factors influencing the fast pyrolysis—chemical vapor generation，such as Py-CVG temperature，argon shield gas flow rate，the amount of sodium format and thiourea was optimized and optimal conditions were determined．The results showed that under optimal conditions of T 500。C，the volumes of 30％sodium formate were 0．2 ml，1 0％(m／v)thiourea were 0．05 ml，and shield gas(argon)flow rate of 300 ml／min，the fluorescence intensity and the quality of arsenic had a good linear relationship(R2=0．998)，detection limit of 0．39 ng，and the RSD of 3．25％．The method was successfully applied to determine trace amount of arsenic in two soil．certified reference materials(GBW07453 and GBW07450)，and the results were found to be in agreement with certified reference values．This method is characterized by low sample consumption，the determination of arsenic can be finished by one time pyrolysis．The method can direct determinate arsenic in soil samples which is no