炼油厂恶臭污染物治理技术研究-化学工程专业论文.docxVIP

浙江工业大学研究生学位论文 浙江工业大学研究生学位论文 炼油厂恶臭污染物治理技术研究 摘要 本文通过对炼油厂各种工况下恶臭污染物排放现状的调查分析，找出在炼油 加工过程中排放的恶臭污染物种类、排放量及对周围环境的影响程度，对固体吸 附法、液相转化法和生物法三类恶臭污染物治理技术进行了实验室试验、现场小 试的应用研究，获得了一系列实验数据，指出了存在的问题，对进一步开展炼油 恶臭污染治理研究工作提供了借鉴。 研究认为：(1)负载碱性金属及过渡金属氧化物的吸附剂A和带有活性物质 和催化剂的吸附剂B双塔串联使用，对脱除硫化氢、硫醇等硫化物有较好效果， 硫容可达14％以上。 (2)在炼化装置恶臭较严重的部位停工吹扫前使用专用的液相转化脱臭剂浸 泡处理，能起到明显的除臭作用。 (3)采用适当的预处理措施和两级生物塔串联的生物滤床技术处理组分复杂 的石化污水处理废气，主要恶臭污染物的去除率为：H2S_97．2％，有机硫化物兰87．2 ％，苯系物93．7％。且在一定浓度范围内，对废气浓度变化的适应性好。 关键词：炼油厂，恶臭污染，恶臭调查，恶臭治理技术 II 浙江工业大学研究生学位论文Study 浙江工业大学研究生学位论文 Study the Odor Pollution Government Technology in the Oil Plant This article，through investigating and analyzing the odor pollutant discharges the present situation to refinery each kind of operating mode，discovers in refines oil the odor pollutant type，the withdrawal and to the environment influence which in the processing process discharges．Three 1(ind of odors pollution government technology, including the solid adsorption，the liquid oxidation absorption and the biological adsorption has been carried on the laboratory experiment，the scene small trial applied research has been further done，a series of empirical datum has been obtained，the existence question had been pointed out,to further developed refines oil the odor pollution government research work to provide the model． The research has suggested： (1)The alkaline metal of load and absorbent A and having active materials and absorbent B twin towers of the catalyst to contact and is used of the metal oxide of transition，having better results to get rid of various kinds of sulphides，such as hydrogen，sulphur alcohol，etc．The sulphur holds can be more than 14％． (2)In builds up the installment odor more serious spot work suspension blows sweeps front uses the special—purpose liquid oxidation deodorizer soaks processing，can play obviously deodorizes role． (3)Adopt proper pretreatment measure or strain bed technical that two biological living beings tower treatment component part contact，complicated petrochemical