PP-ST-DVB及PPS纤维氯甲基化与胺化新工艺研究.pdfVIP

Abstract Abstract Blanc chloromethylation is a kind of very classical reaction, which is a very important method on inducting chloromethyl in benzene ring. The chloromethyl with high chemical reactivity and can be turned into many other groups, which is an important step in the preparation of strong base or weak base polymer materials. However, commonly used chloromethylation reagent, such as ClCH OCH and 2 3 (ClCH ) O, they have the advantages of low price of raw materials, high reactivity, 2 2 good reaction selectivity, but they also have the disadvantages of more volatile, highly unstable, carcinogenicity and have been banned by many industrial countries. HCHO-HCl system is another chloromethylation reagent, but the reaction activity is low, reaction time is long and the yield is not high. In this paper, we use the trimethylchlorosilane (TMCS) and 1,4-bis(chloromethoxy) butane (BCMB) which have non-toxic or low and no carcinogenicity as chloromethylation reagent for the chloromethylation of PP-ST-DVB and PPS fibrous matrix. Then we prepared a strong base ion exchange fiber material through the subsequent functional reaction. The main contents and results were summarized as follows. (1). Studying on the chloromethylation reaction which use PP-ST-DVB fiber as the basic skeleton and TMCS and BCMB as chloromethylation reagent.