硫化钠溶液吸收与电解处理PSA工艺脱附硫化氢-化学工程专业论文.docxVIP

中文摘要本文主要是对变压吸附(PSA)-r艺脱附的硫化氢进行处理，采用硫化钠溶 中文摘要 本文主要是对变压吸附(PSA)-r艺脱附的硫化氢进行处理，采用硫化钠溶 液吸收PSA工艺脱附的H2S，同时对吸收液进行电解，探索天然气脱硫装置小 型化、清洁化的新途径。 针对以上目标，本文首先研究了采用H型隔膜式电解槽以硫化钠溶液为阳 极液、氢氧化钠溶液为阴极液，直接电解回收氢气和硫磺的实验条件(包括阳极 液浓度、反应温度、工作电流密度、prI值)；然后在最佳电解条件下进行了硫化 钠溶液吸收微量硫化氢气体的实验。 电解实验得出硫化钠溶液直接电解的适宜条件为：C№s0．50 mol·L．1，电解 温度55。C～700c，电流密度10 mA／cm2～20 mA／om2，电解液的pH值13．2左右。 在上述条件下，开始电解时阳极生成的硫溶于阳极液中形成多硫化物，并没有明 显的钝化现象发生；而当阳极反应物的转化率达到70％以上时，随着反应物浓 度降低、单质硫含量增大、pH值减小，产物硫会在电极表面析出，使槽压上升、 工作电流下降，因此为保证电解过程的连续、稳定操作，应及时将生成的单质硫 排出体系，并保证阳极液中有较高的反应物(s})浓度。 在一定的条件下，多硫化物和单质硫的转化为一可逆过程(如多硫化物在浓 度增加、温度降低、pn值下降等条件下能重新生成单质硫)，从而使得直接电解 硫化钠溶液回收硫磺成为可能。 吸收实验发现：阳极硫化钠溶液对微量硫化氢有很好的吸收效果。通过理论 计算得出气相传质过程为碱性溶液吸收硫化氢气体的速率决定步骤，为达到较好 的吸收效果吸收液的pn值至少要大于8．57。 关键词：天然气；脱硫；吸收；电解；硫化氢 AbstractTIIis Abstract TIIis article aimed at treating of the PSA desorbed H2S with absorption and electrolysis in the solution of sodium sulfide．we are trying to explore a new process for removing H2S from natural gas，with the objective ofminiature and cleanliness． In view of such goal and the reusage of H2S，appropriate conditions of direct elecliolysis of H2S in alkaline solution was first studied．The anodic oxidation of sodium sulfide formed polysulfide ions，whereas the cathodic product Was hydrogen, with the electrolyte in the cathode chamber being NaOH．In a double—compartment cell ofH type employing ion—exchange membrane as separator,such effects as anolyte concentration,temperature，current density,and pH are discussed．Also the absorption of minor H2S with sodium sulfide under the optimal conditions for electrolysis Was conducted． Electrolytic experiment showed the optimal conditions arc as foUows：Na2S concentration of mole than 0．50 m01．L1，temperature of 55。C～70C，current density of 10 mA／cm2～20 mm／cm2 and pH of 13．2 Or SO．In the original stage，sulfur produced took the form of polysulfides for solving in the anolyte．Only minimal，if any passivation of anode by sulfur product Was observed under these conditions。But when the conversion rate of reactant S玉iS曲o